acetanilide ion

Base Information

• Chemical Name: acetanilide ion
• CAS No.: 61057-08-7
• Molecular Formula: C₈H₈NO
• Molecular Weight: 134.158
• Mol file: 61057-08-7.mol

Synonyms:

Chemical Property of acetanilide ion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of acetanilide ion

There total 11 articles about acetanilide ion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 3.0%

phenylnitrene anion radical (74586-02-0) + acetone (67-64-1) → methyl radical (2229-07-4) + acetone enolate ion (24262-31-5) + anilino radical (2348-49-4) + N-phenylacetamide anion (61057-08-7) + C9H11NO(1-)

Guidance literature:

Product distribution; Mechanism; Rate constant; flowing afterglow apparatus; quadrupole MS-monitoring of the relative concentrations of PhN(-*) and products; relative rate constants for the addition reactions and total absolute constant; a series of carbonyl compounds investigated;

DOI:10.1021/ja00393a032

Reference yield:

acetaldehyde (75-07-0,9002-91-9) + phenylnitrene anion radical (74586-02-0) → methyl radical (2229-07-4) + N-phenylacetamide anion (61057-08-7) + C7H6NO(1-) (55883-40-4)

Guidance literature:

at 24.9 ℃; under 0.5 Torr; Rate constant; Thermodynamic data; collisional rate constant, ΔH^o;

DOI:10.1021/ja00340a010

Reference yield:

acetic acid methyl ester (79-20-9) + phenylnitrene anion radical (74586-02-0) → methoxyl radical (2143-68-2) + anilino radical (2348-49-4) + N-phenylacetamide anion (61057-08-7) + C3H5O2(1-) (2887-49-2,54668-31-4,64723-96-2,84785-11-5,138175-67-4)

Guidance literature:

at 24.9 ℃; under 0.5 Torr; Rate constant; Thermodynamic data; collisional rate constant, ΔH^o;

DOI:10.1021/ja00340a010

upstream raw materials:

acetic acid methyl ester

phenylnitrene anion radical

1,1,1-trifluoro-2-propanone

acetaldehyde

Refernces

• 1、 McDonald, Richard N.,Chowdhury, A. Kasem. "Gas-Phase Nucleophilic Addition Reactions of Phenylnitrene Anion Radical with Certain Carbonyl-Containing Molecules". . p. 674 - 676. Retrieved 2007/10/02.
• 2、 McDonald, Richard N.,Chowdhury, A. Kasem. "Identification of Nucleophilic 1,2- and 1,4-Addition Processes with α,β-Unsaturated Molecules in the Gas Phase". . p. 6146 - 6147. Retrieved 2007/10/02.