Phenylamino

Base Information

• Chemical Name: Phenylamino
• CAS No.: 2348-49-4
• Molecular Formula: C6H6 N
• Molecular Weight: 92.1203
• DSSTox Substance ID: DTXSID70178043
• Nikkaji Number: J1.748.784A,J725.509H
• Mol file: 2348-49-4.mol

Synonyms:Anilino radical;phenylamino;anilino;2348-49-4;benzenaminyl;Amidogen, phenyl-;4-Aminophenylradical;CHEBI:48372;DTXSID70178043

Chemical Property of Phenylamino

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 92.050024196
• Heavy Atom Count: 7
• Complexity: 46.1

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[NH]

Technology Process of Phenylamino

There total 29 articles about Phenylamino which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Cumene hydroperoxide (80-15-9) + aniline (62-53-3) → anilino radical (2348-49-4) + phenyl cumyl nitroxide (34295-23-3) + nitrobenzene (98-95-3,26969-40-4) + Nitrosobenzene (586-96-9) + phenyl cumyloxyl nitroxide

Guidance literature:

In 2,2,4-trimethylpentane; Mechanism; Ambient temperature; Irradiation; var. oxidant, solvent, temp.;

DOI:10.1016/S0040-4020(01)85525-3

Reference yield:

cyclobutanone (1191-95-3) + phenylnitrene anion radical (74586-02-0) → ethene (74-85-1) + anilino radical (2348-49-4) + cyclobutanone enolate anion (67592-89-6) + C8H7NO(1-)

Guidance literature:

at 24.9 ℃; under 0.5 Torr; Rate constant; collisional rate constant;

DOI:10.1021/ja00340a010

Reference yield:

cyclobutanone (1191-95-3) + phenylnitrene anion radical (74586-02-0) → ethene (74-85-1) + anilino radical (2348-49-4) + cyclobutanone enolate anion (67592-89-6) + C8H7NO(1-)

Guidance literature:

Product distribution; Mechanism; Rate constant; flowing afterglow apparatus; quadrupole MS-monitoring of the relative concentrations of PhN(-*) and products; relative rate constants for the addition reactions and total absolute constant; a series of carbonyl compounds investigated;

DOI:10.1021/ja00393a032

upstream raw materials:

pyridine

Aminobenzenradikatkation

picoline

3-Methylpyridine

Refernces

• 1、 Okutsu, Tetsuo,Yano, Kouki,Kawai, Akio,Obi, Kinichi. "Dual Spin Polarization of CIDEP in Benzil/Quencher Systems". . p. 5401 - 5405. Retrieved 1991.
• 2、 Alfassi, Z. B.,Mosseri, S.,Neta, P.. "Reactivities of Chlorine Atoms and Peroxyl Radicals Formed in the Radiolysis of Dichloromethane". . p. 1380 - 1385. Retrieved 2007/10/02.