(η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=S)N=C(OEt)O)*chloroform

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Chemical Name:(η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=S)N=C(OEt)O)*chloroform
CAS No.:610312-01-1
Molecular Formula:CHCl₃*C₄₃H₃₉NO₂P₂RuS
Molecular Weight:916.25
Hs Code.:

Synonyms:

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Chemical Property of (η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=S)N=C(OEt)O)*chloroform

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Technology Process of (η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=S)N=C(OEt)O)*chloroform

There total 1 articles about (η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=S)N=C(OEt)O)*chloroform which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67-66-3,8013-54-5
chloroform

: (η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=NCO2Et)S)

: 610312-01-1
(η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=S)N=C(OEt)O)*chloroform

Guidance literature:: In chloroform; under N2; isomerization of the Ru complex in CHCl3; solvent reduced under vac.; n-pentane added to cause pptn.; after filtration, ppt. washed with n-pentane, dried under vac., and recrystd. from CHCl3/n-pentane (1:3);
DOI:10.1021/om030341w

Reference yield:

: 75-09-2
dichloromethane

: 610312-01-1
(η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=S)N=C(OEt)O)*chloroform

: 610311-98-3
(η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(SCH2Cl)NC(=O)O)

Guidance literature:: In dichloromethane; under N2; react. of the Ru complex with CH2Cl2 for 3 days / high yield;
DOI:10.1021/om030341w

Reference yield:

: 75-09-2
dichloromethane

: (η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=NCO2Et)S)

: 610312-01-1
(η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(=S)N=C(OEt)O)*chloroform

: [(η5-cyclopentadienyl)(Ph2PCH2CH2PPh2)Ru(cyclo-C=C(Ph)C(SCH2Cl)NC(OEt)O)][Cl]

Guidance literature:: In dichloromethane; under N2; CH2Cl2 added in Schlenk flask charged with Cp(dppe)RuC=C(Ph)C(=NCO2Et)S and Cp(dppe)RuC=C(Ph)C(=S)N=C(OEt)O*CHCl3 in ratio of ca. 1:3;resulting soln. stirred at room temp. for hours; not isolated; NMR anal.;
DOI:10.1021/om030341w