Technology Process of 2-chloromercuri-5,10,15,20-tetrakis(4-methylphenyl)porphyrinatonickel(II)
There total 2 articles about 2-chloromercuri-5,10,15,20-tetrakis(4-methylphenyl)porphyrinatonickel(II) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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In
methanol; water; benzene;
byproducts: phenylmercuric chloride, (CH3C6H5)4C20H6N4(HgCl)2Ni, (CH3C6H5)4C20H5N4(HgCl)3Ni; dropwise addn. of 0.94 mmol Hg-acetate in 25 ml dry methanol to a soln. of 0.45 mmol complex in 400 ml C6H6 (under N2), refluxing for 24h, cooling, addn. of 10 ml satd. aq. NaCl-soln., stirring for 1h;; sepn. of organic phase, washing with H2O, filtration, evapn. in vac.; chromy. (SiO2/CH2Cl2/cyclohexane=1:1); monosubstituted complex as 2. fraction; recrystn. from CHCl3/ethanol; elem. anal., UV, IR, (1)H-NMR;;
- Guidance literature:
-
In
methanol; chlorobenzene;
byproducts: (CH3C6H5)4C20H7N4(HgCl)2Ni, (CH3C6H5)4C20H6N4(HgCl)3Ni; dropwise addn. of 0.94 mmol Hg-trifluoroacetate in 19 ml dry methanol to a soln. of 0.34 mmol complex in 250 ml chlorobenzene, refluxing for 18min, cooling, addn. of 10ml satd. aq. NaCl-soln., stirring for 1h;; separation of organic phase, washing with H2O, filtration, evapn. in vac.; chromy. (SiO2/CH2Cl2/cyclohexane=1:1); monosubstituted complex as 2. fraction; recrystn. from CHCl3/ethanol; elem. anal., UV, IR, (1)H-NMR;;
