(μ-PhTe)2Fe2(CO)6

Base Information

Chemical Name:(μ-PhTe)2Fe2(CO)6
CAS No.:193766-10-8
Molecular Formula:C₁₈H₁₀Fe₂O₆Te₂
Molecular Weight:689.168
Hs Code.:

Synonyms:

Suppliers and Price of (μ-PhTe)2Fe2(CO)6

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (μ-PhTe)2Fe2(CO)6

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (μ-PhTe)2Fe2(CO)6

There total 4 articles about (μ-PhTe)2Fe2(CO)6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 14683-12-6
tellurium

: 17685-52-8
triiron dodecarbonyl

: 10545-99-0
sulfur dichloride

: 100-58-3
phenylmagnesium bromide

: 193766-10-8,193829-55-9,25929-13-9
(μ-PhTe)2Fe2(CO)6

: 423767-86-6
((μ-PhTe)Fe2(CO)6)2(μ4-S)

Guidance literature:: In tetrahydrofuran; under N2 atm. Te and PhMgBr in THF were refluxed for 2 h, soln. was cooled to room temp., Fe3(CO)12 was added, stirred for 0.5 h, cooled to -78°C, SCl2 was added, stirred for 20 min, allowed to warm to room temp, stirred for 4 h; solvent was removed, TLC; elem. anal.;
DOI:10.1021/om011039v

Reference yield: 15.0%

: 14683-12-6
tellurium

: 17685-52-8
triiron dodecarbonyl

: 100-58-3
phenylmagnesium bromide

: 14457-70-6
selenium(II) chloride

: 193766-10-8,193829-55-9,25929-13-9
(μ-PhTe)2Fe2(CO)6

: 442202-48-4
[(μ-PhTe)Fe2(CO)6]2(μ4-Se)

Guidance literature:: In tetrahydrofuran; diethyl ether; under N2 atm. Te in THF and RMgBr in Et2O in Et2O were refluxed for 2 h,cooled to room temp., Fe3(CO)12 was added and stirred for 1 h, cooled t o -78°C, SeCl2 in THF was added and stirred for 30 min at -78°C and for 12 h at room temp.; TLC (petroleum ether); elem. anal.;
DOI:10.1021/om020132w

Reference yield: 14.0%

: 14683-12-6
tellurium

: 17685-52-8
triiron dodecarbonyl

: 103-72-0
phenyl isothiocyanate

: 100-58-3
phenylmagnesium bromide

: 76-05-1
trifluoroacetic acid

: 193766-10-8,193829-55-9,25929-13-9
(μ-PhTe)2Fe2(CO)6

: (μ-PhTe)(μ-PhNHC=S)Fe2(CO)6

Guidance literature:: In tetrahydrofuran; diethyl ether; under N2 atm. Te in THF and RMgBr in Et2O in Et2O were refluxd for 2 h, cooled to room temp., Fe3(CO)12 was added and stirred for 1 h, PhNCS wasadded and stirred for 16 h, CF3COOH was added and stirred for 2 h; solvent was removed under reduced pressure, TLC (CH2Cl2/petroleum ether 1:5); elem. anal.;
DOI:10.1021/om020132w