(Z)-Methyl styryl ether

Base Information

• Chemical Name: (Z)-Methyl styryl ether
• CAS No.: 14371-19-8
• Molecular Formula: C9H10O
• Molecular Weight: 134.178
• Mol file: 14371-19-8.mol

Synonyms:(2-methoxyethenyl)benzene;((Z)-2-Methoxy-vinyl)-benzene;(Z)-1-(2-methoxyvinyl)benzene;cis-2-methoxyethenylbenzene;(Z)-(2-methoxyvinyl)benzene;β-methoxystyrene;(Z)-methyl styryl ether;

Chemical Property of (Z)-Methyl styryl ether

Chemical Property:

• Boiling Point: 70 - 72 °C (3 mmHg)
• PSA: 9.23000
• LogP: 2.30370

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z)-Methyl styryl ether

There total 15 articles about (Z)-Methyl styryl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

methanol (67-56-1) + phenylacetylene (536-74-3) → cis-β-methoxystyrene (14371-19-8)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; at 120 ℃; for 10h; Reagent/catalyst; Solvent; Time; Temperature; stereoselective reaction; Inert atmosphere; Schlenk technique;

Reference yield: 75.0%

deuteromethanol (1455-13-6) + phenylacetylene (536-74-3) → cis-β-methoxystyrene (14371-19-8)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; at 120 ℃; for 10h; stereoselective reaction; Inert atmosphere; Schlenk technique;

Reference yield:

methanol (67-56-1) + (E)-phenylethenyl(phenyl)iodonium tetrafluoroborate → iodobenzene (591-50-4) + cis-β-methoxystyrene (14371-19-8) + (E)-(2-methoxyvinyl)benzene (4110-75-2) + phenylacetylene (536-74-3)

Guidance literature:

at 50 ℃; for 50h; Product distribution; Rate constant; Mechanism; effect of additives; rate const. at 60 deg C;

DOI:10.1246/bcsj.72.163

upstream raw materials:

sodium methylate

phenylacetylene

phenylacetaldehyde

dimethyl sulfate

Downstream raw materials:

4-methoxyl-phenylacetylene

α-bromophenylacetaldehyde

2-bromo-1,1-dimethoxy-2-phenylethane

3r-Methoxy-2,2,4c-triphenyl-cyclobutanon-⁽¹⁾