4110-75-2

Basic information

• Product Name: Benzene, [(1E)-2-methoxyethenyl]-
• CAS NO: 4110-75-2
• Molecular Formula: C9H10O
• Molecular Weight: 134.178
• Mol File: 4110-75-2.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Benzene, [(1E)-2-methoxyethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1E)-2-methoxyethenyl]-(4110-75-2)
• EPA Substance Registry System: Benzene, [(1E)-2-methoxyethenyl]-(4110-75-2)

Safety Data

• Hazardous Substances Data: 4110-75-2(Hazardous Substances Data)

Upstream product

• 122-78-1 phenylacetaldehyde 
• 77-78-1 dimethyl sulfate 
• 14371-19-8 cis-β-methoxystyrene 
• 865-33-8 potassium methanolate 
• 536-74-3 phenylacetylene 
• 67-56-1 methanol 
• 100-52-7 benzaldehyde 
• 67-68-5 dimethyl sulfoxide 
• 96-09-3 styrene oxide 
• 333-27-7 methyl trifluoromethanesulfonate 
• 108415-83-4 (E)-β-styryl phenyl selenone 
• 108415-85-6 (Z)-β-styryl phenyl selenone 
• 60466-40-2 (E)-phenyl(styryl)selane 
• 38608-46-7 acetic acid-(α,β-dibromo-phenethyl ester) 

Downstream Products

• 117531-38-1 1-phenyl-1-phenylselenenyl-2,2-dimethoxy ethane 
• 100-52-7 benzaldehyde 
• 98-95-3 nitrobenzene 
• 122744-69-8 trans-Dihydro-3,5,6-triphenyl-1,2,4,5-trioxazine 
• 52807-29-1 N-(4-iodophenyl)benzamide 
• 93-98-1 N-phenyl benzoyl amide 
• 29582-46-5 (Z)-4,4-dimethyl-1-phenylpent-1-en-3-ol 
• 19775-91-8 (E)-4,4-dimethyl-1-phenylpent-1-en-3-ol 
• 6956-56-5 2,2-dimethoxy-1-phenylethanone 
• 795-47-1 (E)-diphenyl(styryl)phosphine oxide 
• 83947-56-2 4,4,5,5-tetramethyl-2-((E)-styryl)-[1,3,2]dioxaborolane 
• 1694-19-5 E-1-(phenyl)-2-(4'-methoxyphenyl)ethene 
• 17024-58-7 (E)-2,4,6-trimethylstilbene 
• 4714-21-0 E-1-methyl-4-styryl-benzene 

Relevant articles and documents

Synthesis of Non-Terminal Alkenyl Ethers, Alkenyl Sulfides, and N-Vinylazoles from Arylaldehydes or Diarylketones, DMSO and O, S, N-Nucleophiles

A transition-metal-free protocol for the synthesis of non-terminal alkenyl ethers, alkenyl sulfides, and N-vinylazoles from arylaldehydes or diarylketones, DMSO and O, S, N-nucleophiles has been reported. In this protocol, 24 examples of non-terminal alkenyl ethers and 28 examples of non-terminal alkenyl sulfides in 72–95% yields have been synthesized within 5 min. Moreover, 27 examples of non-terminal N-vinylazoles with 57–88% yields have also been synthesized within 2 hours. The preliminary mechanism investigations revealed that arylaldehydes or diarylketones offered a carbon atom, DMSO provided a methine and O, S, N-nucleophiles contributed one X atom for constructing C=C?X structure. (Figure presented.).

MeOTf/KI-catalyzed efficient synthesis of 2-arylnaphthalenesviacyclodimerization of styrene oxides

The MeOTf/KI-catalyzed synthesis of 2-arylnaphthalene derivatives from aryl ethylene oxides in alcohol under ambient conditions is described. The present protocol has a higher atom efficiency and wider substrate applicability with excellent yields. The reaction proceeded using the aryl ethylene oxides to give 2-arylnaphthalenes either in homo-coupling or in cross-coupling. The reaction could also be carried out at the gram scale in minutes.

Intermolecular Hydroalkoxylation of Terminal Alkynes Catalyzed by a Dipyrrinato Rhodium(I) Complex with Unusual Selectivity

An operationally simple and atom-economical method for the E-selective preparation of enol ethers is described. A novel dicarbonyl(5-phenyldipyrrinato)rhodium complex, 2, was prepared in four synthetic steps, characterized by X-ray crystallography and NMR