2-Propene-1-sulfonyl chloride

Base Information

• Chemical Name: 2-Propene-1-sulfonyl chloride
• CAS No.: 14418-84-9
• Molecular Formula: C3H5ClO2S
• Molecular Weight: 140.591
• Hs Code.: 2904909090
• Mol file: 14418-84-9.mol

Synonyms:propen-3-yl sulfonyl chloride;2-Propene-1-sulfonyl chloride;Prop-2-en-1-sulfonsaeure-chlorid;prop-2-enesulfonyl chloride;2-propenylsulfonyl chloride;allylsulfonyl chloride;

Chemical Property of 2-Propene-1-sulfonyl chloride

Chemical Property:

• Vapor Pressure: 1.54mmHg at 25°C
• Boiling Point: 175.4oC at 760 mmHg
• Flash Point: 59.9oC
• PSA: 42.52000
• Density: 1.331g/cm3
• LogP: 1.82180
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C

Purity/Quality:

99%, ^*data from raw suppliers

Prop-2-ene-1-sulfonylChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Propene-1-sulfonyl chloride

There total 9 articles about 2-Propene-1-sulfonyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → allylsulfonyl chloride (14418-84-9)

Guidance literature:

propene; With sulfur dioxide; boron trichloride; In dichloromethane; at -196 - -20 ℃; for 3h;

With N-chloro-succinimide; In dichloromethane; at -20 - 20 ℃;

DOI:10.1002/chem.201000164

Reference yield: 85.0%

sodium prop-2-ene-1-sulfonate (2495-39-8) → allylsulfonyl chloride (14418-84-9)

Guidance literature:

With phosgene;

DOI:10.1016/j.bmcl.2007.11.009

Reference yield: 66.0%

allyl bromide (106-95-6) → allylsulfonyl chloride (14418-84-9)

Guidance literature:

allyl bromide; With sodium sulfite; In water; Reflux;

With trichlorophosphate; at 0 ℃; for 4h; Reflux;

DOI:10.1080/14756366.2019.1695795

upstream raw materials:

sodium prop-2-ene-1-sulfonate

allyl bromide

S-allyl ethanethioate

allyl-trimethyl-silane

Downstream raw materials:

3-(3,5-dichloro-phenyl)-1-(prop-2-ene-1-sulfonyl)-imidazolidine-2,4-dione

1-methyl-2-(2-propenyl)-benzene

1-undecene

methyl 2-acetylpent-4-enoate

Refernces

• 1、 Xia, Yong,Wang, Lin,Studer, Armido. "Site-Selective Remote Radical C?H Functionalization of Unactivated C?H Bonds in Amides Using Sulfone Reagents". . p. 12940 - 12944. Retrieved 2018.
• 2、 Ali, Korany A.,Metz, Peter. "Ring closing metathesis and metal-catalyzed cyclopropanation for the preparation of sultone derivatives". . p. 19 - 29. Retrieved 2019.
• 3、 -. "Preparation method of allylsulfonyl chloride". Paragraph 0017-0020. . Retrieved 2021/06/23.
• 4、 Pustenko, Aleksandrs,Nocentini, Alessio,Bala?ova, Anastasija,Alafeefy, Ahmed,Krasavin, Mikhail,?alubovskis, Raivis,Supuran, Claudiu T.. "Aryl derivatives of 3H-1,2-benzoxathiepine 2,2-dioxide as carbonic anhydrase inhibitors". . p. 245 - 254. Retrieved 2019/12/11.