Sodium allylsulfonate

Base Information

• Chemical Name: Sodium allylsulfonate
• CAS No.: 2495-39-8
• Molecular Formula: C3H5NaO3S
• Molecular Weight: 144.127
• Hs Code.: 29041000
• Mol file: 2495-39-8.mol

Synonyms:2-Propene-1-sulfonicacid, sodium salt (8CI,9CI);Allylsulfonic acid, sodium salt;Sodium1-propene-3-sulfonate;Sodium 2-propene-1-sulfonate;Sodium Allyl Sulphonate;

Chemical Property of Sodium allylsulfonate

Chemical Property:

• Appearance/Colour: solid
• Vapor Pressure: 0Pa at 25℃
• Melting Point: 0oC
• Flash Point: 144.124oC
• PSA: 65.58000
• Density: 1.206 g/cm³
• LogP: 0.79840
• Storage Temp.: -70°C
• Water Solubility.: 4 g/100 mL

Purity/Quality:

99% ^*data from raw suppliers

Sodium Allylsulfonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi,N
• Hazard Codes: Xi,N
• Statements: 36/37/38-50/53-41
• Safety Statements: 24/25-61-60-39-26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Sodium allyl sulfonate is used as a basic brightener in nickel electroplating baths. It is also used as pharmaceutical intermediates. Sodium Allylsulfonate is used as a brightener for nickel electroplating as well as in the dyeing of acryilic fibers.

Technology Process of Sodium allylsulfonate

There total 4 articles about Sodium allylsulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.93%

4-tert-Butylcatechol (98-29-3) → sodium prop-2-ene-1-sulfonate (2495-39-8)

Guidance literature:

With sodium metabisulfite; N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide; In water; at 40 - 50 ℃; under 2250.23 Torr; Temperature; Reagent/catalyst; Pressure;

Reference yield: 78.0%

allyl bromide (106-95-6) → sodium prop-2-ene-1-sulfonate (2495-39-8)

Guidance literature:

With sodium sulfite;

DOI:10.1039/a700656j

Reference yield: 75.0%

3-chloroprop-1-ene (107-05-1) → sodium prop-2-ene-1-sulfonate (2495-39-8)

Guidance literature:

With sodium sulfite; In ethanol; for 4h; Heating;

DOI:10.1055/s-2003-40201

upstream raw materials:

3-chloroprop-1-ene

allyl bromide

sodium sulfite

4-tert-Butylcatechol

Downstream raw materials:

3-hydroxypropanesulfonic acid

hydrogen sulfide

sulfur dioxide

sulfur

Refernces

• 1、 Ali, Korany A.,Metz, Peter. "Ring closing metathesis and metal-catalyzed cyclopropanation for the preparation of sultone derivatives". . p. 19 - 29. Retrieved 2019/04/17.
• 2、 Górski, Bartosz,Basiak, Dariusz,Talko, Alicja,Basak, Tymoteusz,Mazurek, Tomasz,Barbasiewicz, Micha?. "Olefination with Sulfonyl Halides and Esters: E-Selective Synthesis of Alkenes from Semistabilized Carbanion Precursors". supporting information. p. 1774 - 1784. Retrieved 2018/04/27.