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CAS No.: | 14418-84-9 |
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Name: | 2-Propene-1-sulfonyl chloride |
Article Data: | 31 |
Molecular Structure: | |
Formula: | C3H5ClO2S |
Molecular Weight: | 140.591 |
Synonyms: | propen-3-yl sulfonyl chloride;2-Propene-1-sulfonyl chloride;Prop-2-en-1-sulfonsaeure-chlorid;prop-2-enesulfonyl chloride;2-propenylsulfonyl chloride;allylsulfonyl chloride; |
Density: | 1.331g/cm3 |
Boiling Point: | 175.4oC at 760 mmHg |
Flash Point: | 59.9oC |
PSA: | 42.52000 |
LogP: | 1.82180 |
propene
allylsulfonyl chloride
Conditions | Yield |
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Stage #1: propene With sulfur dioxide; boron trichloride In dichloromethane at -196 - -20℃; for 3h; Stage #2: With N-chloro-succinimide In dichloromethane at -20 - 20℃; | 89% |
Stage #1: propene With sulfur dioxide; boron trichloride In dichloromethane ene reaction; Stage #2: With N-chloro-succinimide | 81% |
Stage #1: propene With sulfur dioxide; boron trichloride In dichloromethane at -196 - -20℃; Inert atmosphere; Stage #2: With N-chloro-succinimide In dichloromethane at -20 - 20℃; Inert atmosphere; | 81% |
sodium prop-2-ene-1-sulfonate
allylsulfonyl chloride
Conditions | Yield |
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With phosgene | 85% |
With thionyl chloride; N,N-dimethyl-formamide for 12h; Heating; | |
With thionyl chloride at 70℃; for 36h; |
allyl bromide
allylsulfonyl chloride
Conditions | Yield |
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Stage #1: allyl bromide With sodium sulfite In water Reflux; Stage #2: With trichlorophosphate at 0℃; for 4h; Reflux; | 66% |
With water; sodium sulfite; trichlorophosphate Yield given. Multistep reaction; | |
Stage #1: allyl bromide With sodium sulfite In water at 60 - 125℃; Substitution; Stage #2: With trichlorophosphate at 130℃; Chlorination; Further stages.; | |
Stage #1: allyl bromide With sodium sulfite In water Reflux; Stage #2: With trichlorophosphate for 4h; Reflux; |
S-allyl ethanethioate
allylsulfonyl chloride
Conditions | Yield |
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With hydrogenchloride; N-chloro-succinimide In acetonitrile at 10℃; | 6.1% |
allylsulfonyl chloride
Conditions | Yield |
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With chlorine |
allylsulfonyl chloride
Conditions | Yield |
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With trichlorophosphate at 105℃; |
allyl-trimethyl-silane
allylsulfonyl chloride
Conditions | Yield |
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Stage #1: allyl-trimethyl-silane With sulfur dioxide In acetonitrile Stage #2: With N-chloro-succinimide In acetonitrile |
allylmagnesium bromide
allylsulfonyl chloride
Conditions | Yield |
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Stage #1: allylmagnesium bromide With 1,4-diazabicyclo [2.2.2] octane-1,4-diium-1,4-disulfinate In tetrahydrofuran at -40℃; for 1h; Inert atmosphere; Stage #2: With sulfuryl dichloride In tetrahydrofuran at -40 - 20℃; Inert atmosphere; |
Conditions | Yield |
---|---|
With dmap; triethylamine In dichloromethane at 0℃; Inert atmosphere; | 95% |
With dmap; triethylamine In dichloromethane at 0℃; for 1h; | 91% |
With dmap; triethylamine In dichloromethane at 0℃; for 1h; | 91% |
With triethylamine In dichloromethane at 20℃; for 0.5h; | 83% |
With triethylamine In dichloromethane at 0 - 20℃; | 83% |
homoalylic alcohol
allylsulfonyl chloride
but-3-enyl prop-2-ene-1-sulfonate
Conditions | Yield |
---|---|
With dmap; triethylamine In dichloromethane at 0℃; for 0.75h; | 95% |
With dmap; triethylamine In dichloromethane at 0℃; for 0.75h; | 95% |
With dmap; triethylamine In dichloromethane at 0℃; Inert atmosphere; | 95% |