Ethanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-

Base Information

Chemical Name:Ethanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-
CAS No.:145533-43-3
Molecular Formula:C₂₁H₂₀NP
Molecular Weight:317.37
Hs Code.:
DSSTox Substance ID:DTXSID10478514
Nikkaji Number:J1.021.592G
Mol file:145533-43-3.mol

Synonyms:Ethanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-;145533-43-3;DTXSID10478514;N-(2-(Diphenylphosphino)benzylidene)ethanamine

Suppliers and Price of Ethanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ethanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-

Chemical Property:

PSA：25.95000
LogP:3.88360
XLogP3:4.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:5
Exact Mass:317.133336640
Heavy Atom Count:23
Complexity:337

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCN=CC1=CC=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Ethanamine, N-[[2-(diphenylphosphino)phenyl]methylene]-

There total 1 articles about Ethanamine, N-[[2-(diphenylphosphino)phenyl]methylene]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 50777-76-9
(2-formylphenyl)(diphenyl)phosphine

: 75-04-7,85404-22-4
ethylamine

: 145533-43-3
N-[2-(diphenylphosphanyl)benzylidene]-N-ethylamine

Guidance literature:: Heating;
DOI:10.1039/DT9920003371

Reference yield: 91.0%

: 60969-19-9
thallium(I) hexafluorophosphate

: diμ-chlorotetrakis(η2-cyclooctene)diiridium(I)

: 145533-43-3
N-[2-(diphenylphosphanyl)benzylidene]-N-ethylamine

: 154889-07-3
{((C₆H₅)2PC₆H₄CHNC₂H₅)2Ir}⁽¹⁺⁾*PF₆^(1-)={((C₆H₅)2PC₆H₄CHNC₂H₅)2Ir}PF₆

Guidance literature:: In acetone; byproducts: TlCl; N2 atmosphere; Ir-compd. is added to soln. of P-compd. in acetone at room temp., addn. of TlPF6 with stirring; filtration after 20 min, addn. of n-butanol, slow evapn. of solvent under N2, elem. anal.;

Reference yield: 85.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 143-66-8
sodium tetraphenyl borate

: 145533-43-3
N-[2-(diphenylphosphanyl)benzylidene]-N-ethylamine

: 146164-38-7
Rh((C₆H₅)2PC₆H₄CHNCH₂CH₃)2⁽¹⁺⁾*B(C₆H₅)4^(1-)=(Rh((C₆H₅)2PC₆H₄CHNCH₂CH₃)2)B(C₆H₅)4

Guidance literature:: In ethanol; dichloromethane; react. under dry N2; addn. of ligand in CH2Cl2 to a soln. of Rh-complex in CH2Cl2, addn. of NaBPh4 in EtOH; evapn., recrystn. from dichloroethane-butanol; elem. anal.;
DOI:10.1039/DT9920003371