Methyl 2,2-diphenylethenyl sulfide

Base Information

• Chemical Name: Methyl 2,2-diphenylethenyl sulfide
• CAS No.: 15096-10-3
• Molecular Formula: C15H14S
• Molecular Weight: 226.342
• Hs Code.: 2930909090
• Mol file: 15096-10-3.mol

Synonyms:Methyl 2,2-diphenylethenyl sulfide;[2-(Methylsulfanyl)-1-phenylvinyl]benzene;Benzene,1,1'-[(methylthio)ethenylidene]bis;

Chemical Property of Methyl 2,2-diphenylethenyl sulfide

Chemical Property:

• Melting Point: 74.0-74.5 °C(Solv: ethanol (64-17-5))
• Boiling Point: 115-120 °C
• PSA: 25.30000
• Density: 1.073±0.06 g/cm3(Predicted)
• LogP: 4.43880

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl 2,2-diphenylethenyl sulfide

There total 18 articles about Methyl 2,2-diphenylethenyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Dimethyldisulphide (624-92-0) + Ph2CCHHgBr (67341-86-0) → methyl 2,2-diphenylethenyl sulfide (15096-10-3)

Guidance literature:

In benzene; at 35 - 45 ℃; for 8h; Irradiation;

DOI:10.1021/ja00545a054

Reference yield: 99.0%

1,1-Diphenylethylene (530-48-3) + sodium methansulfinate (20277-69-4) → methyl 2,2-diphenylethenyl sulfide (15096-10-3)

Guidance literature:

With hydrogen iodide; In toluene; at 75 ℃; for 15h;

Reference yield: 90.0%

1,1-Diphenylethylene (530-48-3) → methyl 2,2-diphenylethenyl sulfide (15096-10-3)

Guidance literature:

With trifluoroacetic anhydride; In tetrachloromethane; at -20 ℃;

DOI:10.1016/S0040-4020(01)98953-7

upstream raw materials:

1,1-Diphenylethylene

S-methyl methanethiosulfinate

benzophenone

diethyl 1-(methylthio)methylphosphonate

Downstream raw materials:

(S)-(-)-methyl-(2,2-diphenyl) vinyl sulfoxide

C₁₅H₁₄OS

(2,2-diphenyl)ethenyltriphenylgermane

Refernces

• 1、 -. "Method for preparing aryl vinyl alkyl thioether through C/C-S monatomic assembly process". Paragraph 0096; 0100-0101; 0198-0200. . Retrieved 2022/04/08.
• 2、 Wang, Bo-Wen,Jiang, Kai,Li, Jian-Xiao,Luo, Shi-He,Wang, Zhao-Yang,Jiang, Huan-Feng. "1,1-Diphenylvinylsulfide as a Functional AIEgen Derived from the Aggregation-Caused-Quenching Molecule 1,1-Diphenylethene through Simple Thioetherification". supporting information. p. 2338 - 2343. Retrieved 2020/01/24.