2-phenyl-1H-perimidine

Base Information

• Chemical Name: 2-phenyl-1H-perimidine
• CAS No.: 15666-84-9
• Molecular Formula: C17H12N2
• Molecular Weight: 244.296
• Mol file: 15666-84-9.mol

Synonyms:1H-Perimidine,2-phenyl;2-Phenyl-perimidin;2-Phenyl-1H-perimidin;2-Phenylperimidine;

Chemical Property of 2-phenyl-1H-perimidine

Chemical Property:

• PSA: 28.68000
• LogP: 4.38310

Purity/Quality:

2-PHENYL-1H-PERIMIDINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-phenyl-1H-perimidine

There total 14 articles about 2-phenyl-1H-perimidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-phenyl-2,3-dihydro-1H-1H-2,3-dihydro1H-2,3-dihydroperimidine (19564-07-9) → 2-phenylperimidine (15666-84-9)

Guidance literature:

With sodium disulfite; In ethanol; water; for 2h; Heating;

DOI:10.1007/BF00475399

Reference yield: 97.0%

naphthalene-1,8-diamine (479-27-6) → 2-phenylperimidine (15666-84-9)

Guidance literature:

In dichloromethane; at 20 ℃; for 7.5h;

DOI:10.1002/chem.200305138

Reference yield: 95.0%

benzaldehyde (100-52-7) + naphthalene-1,8-diamine (479-27-6) → 2-phenylperimidine (15666-84-9)

Guidance literature:

With sodium metabisulfite; In ethanol; for 1h; Heating;

DOI:10.1080/00397919108055450

upstream raw materials:

1,3-diphenylpropanedione

naphthalene-1,8-diamine

benzoic acid anhydride

(4-dimethylamino-phenylimino)-phenyl-acetonitrile

Downstream raw materials:

2-phenylperimidine-6⁽⁷⁾-carbaldehyde

2,6-diphenyl-1,3,7-triazapyrene

2,6,8-triphenyl-1,3,7-triazapyrene

2,8-diphenyl-1,3,6-triazapyrene

Refernces

• 1、 Smellie, Iain A.S.,Fromm, Andreas,Paton, R. Michael. "A new route to 2-substituted perimidines based on nitrile oxide chemistry". . p. 4104 - 4106. Retrieved 2009.
• 2、 Amrollahi,Ashayeri-Harati. "Magnetic Graphene Oxide Bearing ZrO2 as a New Composite Catalyst for the Synthesis of 1H-Perimidines". . p. 282 - 289. Retrieved 2020/07/03.
• 3、 Schwob, Tobias,Ade, Mirco,Kempe, Rhett. "A Cobalt Catalyst Permits the Direct Hydrogenative Synthesis of 1H-Perimidines from a Dinitroarene and an Aldehyde". . p. 3013 - 3017. Retrieved 2019/05/15.