Aziridine, 1-[(4-methylphenyl)sulfonyl]-2-octyl-

Base Information

• Chemical Name: Aziridine, 1-[(4-methylphenyl)sulfonyl]-2-octyl-
• CAS No.: 159659-19-5
• Molecular Formula: C17H27NO2S
• Molecular Weight: 309.473
• DSSTox Substance ID: DTXSID30373077
• Nikkaji Number: J779.487H
• Mol file: 159659-19-5.mol

Synonyms:Aziridine, 1-[(4-methylphenyl)sulfonyl]-2-octyl-;159659-19-5;1-Tosyl-2-octylaziridine;DTXSID30373077

Chemical Property of Aziridine, 1-[(4-methylphenyl)sulfonyl]-2-octyl-

Chemical Property:

• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 9
• Exact Mass: 309.17625028
• Heavy Atom Count: 21
• Complexity: 394

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCCCCCC1CN1S(=O)(=O)C2=CC=C(C=C2)C

Technology Process of Aziridine, 1-[(4-methylphenyl)sulfonyl]-2-octyl-

There total 6 articles about Aziridine, 1-[(4-methylphenyl)sulfonyl]-2-octyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

1-Decene (872-05-9,17438-89-0,25189-70-2) + 4-methyl-N-[(2-propoxyphenyl)-λ3-iodanylidene]benzenesulfonamide (1338062-05-7) → 1-(4-methylphenylsulfonyl)-2-octylaziridine (159659-19-5)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); In acetonitrile; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/chem.201102265

Reference yield: 80.0%

1-Decene (872-05-9,17438-89-0,25189-70-2) + [N-(p-tolylsulfonyl)imino]phenyliodinane (55962-05-5) → 1-(4-methylphenylsulfonyl)-2-octylaziridine (159659-19-5)

Guidance literature:

With 2C₃₆H₂₀AlF₂₄O₄^(1-)*C₄₂H₃₀CuN₆⁽²⁺⁾; In dichloromethane; at 25 ℃; for 0.0333333h; Inert atmosphere;

DOI:10.1039/c1dt10280j

Reference yield: 80.0%

1-Decene (872-05-9,17438-89-0,25189-70-2) + bromamine T (41085-71-6) → 1-(4-methylphenylsulfonyl)-2-octylaziridine (159659-19-5)

Guidance literature:

With 5A molecular sieve; copper dichloride; In acetonitrile; for 0.2h; microwave irradiation;

DOI:10.1021/jo000013v

upstream raw materials:

1-Decene

chloroamine-T

bromamine T

dibromamine-T

Refernces

• 1、 Sengupta, Gargi,Pandey, Pragati,De, Subhabrata,Ramapanicker, Ramesh,Bera, Jitendra K.. "A bromo-capped diruthenium(i,i) N-heterocyclic carbene compound for in situ bromine generation with NBS: Catalytic olefin aziridination reactions". . p. 11917 - 11924. Retrieved 2018/09/10.
• 2、 Li, Yang,He, Jiayue,Khankhoje, Vineeta,Herdtweck, Eberhardt,Koehler, Klaus,Storcheva, Oksana,Cokoja, Mirza,Kuehn, Fritz E.. "Copper(ii) complexes incorporating poly/perfluorinated alkoxyaluminate-type weakly coordinating anions: Syntheses, characterization and catalytic application in stereoselective olefin aziridination". scheme or table. p. 5746 - 5754. Retrieved 2011/08/02.