(2-([1',2',7':η-2'-(phenyl(tert-butyl)methylene)](phenyl-κC(3')))-pyrimidine-κN(1))(tricarbonylmanganese(I)-κN(2))tetracarbonylmanganese(I)

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Chemical Name:(2-([1',2',7':η-2'-(phenyl(tert-butyl)methylene)](phenyl-κC(3')))-pyrimidine-κN(1))(tricarbonylmanganese(I)-κN(2))tetracarbonylmanganese(I)
CAS No.:886359-02-0
Molecular Formula:C₂₈H₂₀Mn₂N₂O₇
Molecular Weight:606.352
Hs Code.:

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Chemical Property of (2-([1',2',7':η-2'-(phenyl(tert-butyl)methylene)](phenyl-κC(3')))-pyrimidine-κN(1))(tricarbonylmanganese(I)-κN(2))tetracarbonylmanganese(I)

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Technology Process of (2-([1',2',7':η-2'-(phenyl(tert-butyl)methylene)](phenyl-κC(3')))-pyrimidine-κN(1))(tricarbonylmanganese(I)-κN(2))tetracarbonylmanganese(I)

There total 1 articles about (2-([1',2',7':η-2'-(phenyl(tert-butyl)methylene)](phenyl-κC(3')))-pyrimidine-κN(1))(tricarbonylmanganese(I)-κN(2))tetracarbonylmanganese(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

: 75-09-2
dichloromethane

: 748802-52-0
[2-(phenyl-κC2',κC2'')pyrimidine-(κN1,κN2)]bis(tetracarbonylmanganese(I))

: 83922-79-6
(1-diazo-2,2-dimethylpropyl)benzene

: 886359-03-1
(2-[1',2',7':η-2'-(phenyl(tert-butyl)methylenephenyl)]pyrimidine-κN(1))tricarbonylmanganese(I)

: 886359-02-0
(2-([1',2',7':η-2'-(phenyl(tert-butyl)methylene)](phenyl-κC(3')))-pyrimidine-κN(1))(tricarbonylmanganese(I)-κN(2))tetracarbonylmanganese(I)

: 886359-05-3
(2-[1',2',7':η-2'-(phenyl(tert-butyl)methylene-3'-(tert-butyl))(tricarbonyl(η5-phenyl)manganese(I))methylene]pyrimidine-κN(1))tricarbonylmanganese(I)

: (2-[1',2',7':η-2'-(phenyl(tert-butyl)methylene-3'-(2,2-dimethyl-1-phenylpropylidene)hydrazone)]phenylpyrimidine-κN(1))-tricarbonylmanganese(I)*0.5(dichloromethane)

Guidance literature:: In toluene; under Ar; Mn-contg. compd. (0.42 mmol) was dissolved in toluene and the soln. was brought to reflux; a soln. of diazo-compd. (1.6 mmol) in toluene was added over 25 min; the mixt. was left to boil for 25 min; silica gel was added to the soln. and the suspn. was stripped of solvent; chromy. (4°C) over deactivated silica gel/n-hexane (n-hexane-CH2Cl2 (9:1) for elution); elem. anal.;
DOI:10.1039/b513322j