Phenanthrene-4,5-dicarbaldehyde

Base Information

• Chemical Name: Phenanthrene-4,5-dicarbaldehyde
• CAS No.: 16162-34-8
• Molecular Formula: C16H10O2
• Molecular Weight: 234.254
• DSSTox Substance ID: DTXSID40562177
• Nikkaji Number: J356.923C
• Wikidata: Q82446220
• Mol file: 16162-34-8.mol

Synonyms:PHENANTHRENE-4,5-DICARBALDEHYDE;16162-34-8;SCHEMBL4944634;DTXSID40562177

Chemical Property of Phenanthrene-4,5-dicarbaldehyde

Chemical Property:

• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 234.068079557
• Heavy Atom Count: 18
• Complexity: 293

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C(=C1)C=O)C3=C(C=CC=C3C=O)C=C2

Technology Process of Phenanthrene-4,5-dicarbaldehyde

There total 2 articles about Phenanthrene-4,5-dicarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

pyrene (129-00-0) → 4,5-phenanthrene-8,9-dicarbaldehyde (16162-34-8) + pyrene-4,5-dione (6217-22-7)

Guidance literature:

With ruthenium trichloride; sodium periodate; In dichloromethane; water; acetonitrile; at 21.84 ℃;

DOI:10.1002/chem.201800423

Reference yield:

pyrene (129-00-0) → phthalic anhydride (85-44-9) + xanth-9-one (90-47-1) + pentadecane (629-62-9) + n-docosane (629-97-0) + n-hexacosane (630-01-3) + tetradecane (629-59-4) + Hexadecane (544-76-3) + Diethylene glycol monobutyl ether (112-34-5,9004-77-7) + n-butyl isobutyrate (97-87-0) + heneicosane (629-94-7) + n-tricosane (638-67-5) + tetracosane (646-31-1) + n-pentacosane (629-99-2) + cyclopenta[def]phenanthrene (203-63-4) + 1,2-benzenedicarboxylic acid diisooctyl ether + 2,6-di-tert-butyl-4-methyl-phenol (128-37-0) + Diethyl phthalate (84-66-2) + Phthalic acid dibutyl ester (84-74-2) + 4H-Cyclopenta[def]phenanthrene (203-64-5) + benzyl n-butyl phthalate (85-68-7) + 1,1'-Biphenyl-2,2',6,6'-tetracarboxaldehyde (4371-26-0) + 4,5-phenanthrene-8,9-dicarbaldehyde (16162-34-8) + 1-hexadecylcarboxylic acid (57-10-3) + 6-propyltridecane (55045-10-8)

Guidance literature:

With oxygen; ozone; In water; for 0.25 - 2h;

Reference yield: 92.0%

4,5-phenanthrene-8,9-dicarbaldehyde (16162-34-8) → 1,3-Dihydrophenanthro<4,5-cde>oxepine (7499-80-1)

Guidance literature:

With triethylsilane; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; for 0.75h; Ambient temperature;

DOI:10.1039/a802928h

upstream raw materials:

pyrene

Downstream raw materials:

C₂₂H₁₅NO₂

1,3-Dihydrophenanthro<4,5-cde>oxepine