But-3-enyl-(chloromethyl)-dimethylsilane

Base Information

• Chemical Name: But-3-enyl-(chloromethyl)-dimethylsilane
• CAS No.: 33558-80-4
• Molecular Formula: C7H15 Cl Si
• Molecular Weight: 162.735
• NSC Number: 96801
• DSSTox Substance ID: DTXSID60955188
• Wikidata: Q82934674
• Mol file: 33558-80-4.mol

Synonyms:33558-80-4;NSC96801;DTXSID60955188;NSC-96801;AKOS006381986;(But-3-en-1-yl)(chloromethyl)dimethylsilane

Chemical Property of But-3-enyl-(chloromethyl)-dimethylsilane

Chemical Property:

• Vapor Pressure: 2.4mmHg at 25°C
• Boiling Point: 166°C at 760 mmHg
• Flash Point: 47.8°C
• Density: 0.873g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 162.0631547
• Heavy Atom Count: 9
• Complexity: 88.9

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(CCC=C)CCl

Technology Process of But-3-enyl-(chloromethyl)-dimethylsilane

There total 2 articles about But-3-enyl-(chloromethyl)-dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

1-bromo-4-butene (5162-44-7) + Chloro(chloromethyl)dimethylsilane (1719-57-9) → (but-3-enyl)(chloromethyl)dimethylsilane (33558-80-4)

Guidance literature:

1-bromo-4-butene; With magnesium; In diethyl ether; at 23 ℃; for 3h;

Chloro(chloromethyl)dimethylsilane; In diethyl ether; for 36h; Heating;

DOI:10.1002/hlca.200490152

Reference yield:

Chloro(chloromethyl)dimethylsilane (1719-57-9) + 3-butenylmagnesium chloride (56039-93-1) → (but-3-enyl)(chloromethyl)dimethylsilane (33558-80-4)

Guidance literature:

DOI:10.1016/S0022-328X(00)87515-4

Reference yield:

(but-3-enyl)(chloromethyl)dimethylsilane (33558-80-4) → 1,1-dimethyl-1-silacyclohexane (4040-74-8) + 1,1,3-trimethyl-1-silacyclopentane (17936-93-5) + but-3-en-1-yltrimethylsilane (763-13-3) + C7H15Si

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In various solvent(s); at 25 ℃; Irradiation;

DOI:10.1021/ja00407a058

upstream raw materials:

Chloro(chloromethyl)dimethylsilane

3-butenylmagnesium chloride

1-bromo-4-butene

Downstream raw materials:

1,1-dimethyl-1-silacyclohexane

1,1,3-trimethyl-1-silacyclopentane

but-3-en-1-yltrimethylsilane