cis-2-Tetradecene

Base Information

• Chemical Name: cis-2-Tetradecene
• CAS No.: 1652-97-7
• Molecular Formula: C14H28
• Molecular Weight: 196.376
• UNII: 6O5S0Y06VQ
• Nikkaji Number: J364.010H
• Wikidata: Q27265221
• Mol file: 1652-97-7.mol

Synonyms:cis-2-tetradecene;(Z)-2-Tetradecene;2-Tetradecene, (Z)-;2-Tetradecene, (2Z)-;(2Z)-2-Tetradecene;UNII-6O5S0Y06VQ;6O5S0Y06VQ;35953-53-8;(Z)-tetradec-2-ene;(2E)-2-Tetradecene;2-Tetradecene, trans-;OBDUMNZXAIUUTH-HYXAFXHYSA-N;1652-97-7;Q27265221

Chemical Property of cis-2-Tetradecene

Chemical Property:

• PSA: 0.00000
• LogP: 5.48340
• XLogP3: 7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 10
• Exact Mass: 196.219100893
• Heavy Atom Count: 14
• Complexity: 113

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCCCCCCCCC=CC
• Isomeric SMILES: CCCCCCCCCCC/C=C\C

Technology Process of cis-2-Tetradecene

There total 9 articles about cis-2-Tetradecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

methanol (67-56-1) + tetradecan-2-yl phenyl selenide (89357-91-5) → 1-tetradecene (1120-36-1) + tetradec-2-ene (1652-97-7) + 2-methoxytetradecane (88959-02-8)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; Ambient temperature;

DOI:10.1039/c39830001501

Reference yield: 90.0%

1-tetradecene (1120-36-1) → tetradecan-2-one (2345-27-9) + tetradec-2-ene (1652-97-7)

Guidance literature:

With water; copper(l) chloride; In tetrahydrofuran; at 20 ℃; for 36h; under 759.826 Torr;

DOI:10.1002/cctc.201500241

Reference yield: 51.0%

acetic acid (64-19-7,77671-22-8) + trans-(1-dimethyl(phenyl)silyl)-2-undecylcyclopropane → 1-tetradecene (1120-36-1) + 1-ethyldodecyl acetate (51354-23-5) + tetradec-2-ene (1652-97-7) + 3-acetoxy-1-dimethyl-(phenyl)silyltetradecane

Guidance literature:

With boron trifluoride diacetate; In dichloromethane; for 4h; Yields of byproduct given; Ambient temperature;

DOI:10.1080/00397919308011254

upstream raw materials:

methanol

tetradecan-2-yl phenyl selenide

2-methyl-tetradecanoic acid ; sodium-salt

tetradecan-1-yl phenyl telluride

Downstream raw materials:

lauric acid