[Rh(acetate)(CO)(3-(diphenylphosphino)benzenesulfonic acid)2]

Base Information

• Chemical Name: [Rh(acetate)(CO)(3-(diphenylphosphino)benzenesulfonic acid)2]
• CAS No.: 872611-84-2
• Molecular Formula: C₃₉H₃₃O₉P₂RhS₂
• Molecular Weight: 874.671
• Mol file: 872611-84-2.mol

Synonyms:

Chemical Property of [Rh(acetate)(CO)(3-(diphenylphosphino)benzenesulfonic acid)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Rh(acetate)(CO)(3-(diphenylphosphino)benzenesulfonic acid)2]

There total 1 articles about [Rh(acetate)(CO)(3-(diphenylphosphino)benzenesulfonic acid)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Rh(acetate)(3-(diphenylphosphino)benzenesulfonic acid)3] + carbon monoxide (201230-82-2) → [Rh(acetate)(CO)(3-(diphenylphosphino)benzenesulfonic acid)2] (872611-84-2)

Guidance literature:

In ethanol; under N2 or Ar; Rh complex suspended in fresh EtOH; CO bubbled at room temp. overnight; filtered; ppt. washed with EtOH; dried; elem. anal.;

DOI:10.1139/v05-088

Reference yield:

[Rh(acetate)(CO)(3-(diphenylphosphino)benzenesulfonic acid)2] (872611-84-2) + 3-(diphenylphosphine)-benzenesulfonic acid (16704-71-5) + water (7732-18-5) + hydrogen (1333-74-0) → [RhH(CO)(3-(diphenylphosphino)benzenesulfonic acid)2]

Guidance literature:

With sodium perchlorate; In water; under Ar; aq. soln. of Rh complex reacted with H2 (1 bar) in presence ofexcess of ligand at room temp.; pH 4-10 (KOH or HClO4), ionic strength 0.1 mol/l (NaClO4); Kinetics;

DOI:10.1139/v05-088

upstream raw materials:

carbon monoxide