Cyclohexanone, 2,3-dimethyl-, (2R,3R)-

Base Information

Chemical Name:Cyclohexanone, 2,3-dimethyl-, (2R,3R)-
CAS No.:167073-61-2
Molecular Formula:C₈H₁₄O
Molecular Weight:126.199
Hs Code.:
DSSTox Substance ID:DTXSID50462891
Nikkaji Number:J907.900I
Wikidata:Q82287517
Mol file:167073-61-2.mol

Synonyms:Cyclohexanone, 2,3-dimethyl-, (2R,3R)-;167073-61-2;SCHEMBL12450166;DTXSID50462891

Suppliers and Price of Cyclohexanone, 2,3-dimethyl-, (2R,3R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Cyclohexanone, 2,3-dimethyl-, (2R,3R)-

Chemical Property:

XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:126.104465066
Heavy Atom Count:9
Complexity:118

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1CCCC(=O)C1C
Isomeric SMILES:C[C@@H]1CCCC(=O)[C@@H]1C

Technology Process of Cyclohexanone, 2,3-dimethyl-, (2R,3R)-

There total 3 articles about Cyclohexanone, 2,3-dimethyl-, (2R,3R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1121-18-2
2-methyl-2-cyclohexen-1-one

: 167073-60-1
(2S,3R)-2,3-dimethylcyclohexan-1-one

: 167073-61-2
cis-2,3-dimethylcyclohexanone

Guidance literature:: With copper(I) thiophene-2-carboxylate; trimethylaluminum; (3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-bis-(1-phenyl-ethyl)-amine; In diethyl ether; n-heptane; at -30 ℃; Overall yield = 61 percent; Overall yield = 7.46 g; Inert atmosphere;
DOI:10.1002/chem.202004847

Reference yield:

: 2207-01-4
cis-1,2-dimethylcyclohexane

: 7722-84-1
dihydrogen peroxide

: 1174149-07-5
trans-1,2-dimethylcyclohexan-1-ol

: 1174149-25-7
(1R,2S)-1,2-dimethylcyclohexanol

: 167073-61-2
cis-2,3-dimethylcyclohexanone

: 75364-88-4
(3S,4R)-3,4-dimethylcyclohexanone

Guidance literature:: With cis-(N,N′-dineopentyl-N,N′-bis(2-pyridylmethyl)-1,2-ethanediamine) bis(trifluoromethanesulfonato) iron(II) dihydrate; In acetonitrile; at 24.84 ℃;
DOI:10.1021/ic402501k

Reference yield:

: 2207-01-4
cis-1,2-dimethylcyclohexane

: 1174149-07-5
trans-1,2-dimethylcyclohexan-1-ol

: 167073-61-2
cis-2,3-dimethylcyclohexanone

: 75364-88-4
(3S,4R)-3,4-dimethylcyclohexanone

Guidance literature:: With Δ-[Fe(CF3SO3)2((R,R,R)-MCPP)]; dihydrogen peroxide; acetic acid; In acetonitrile; Reagent/catalyst; Overall yield = 58 %Chromat.; regioselective reaction;
DOI:10.1021/jo302196q