Benzenecarbothioic acid, O-phenyl ester

Base Information

• Chemical Name: Benzenecarbothioic acid, O-phenyl ester
• CAS No.: 16911-57-2
• Molecular Formula: C13H10OS
• Molecular Weight: 214.288
• Mol file: 16911-57-2.mol

Synonyms:

Chemical Property of Benzenecarbothioic acid, O-phenyl ester

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenecarbothioic acid, O-phenyl ester

There total 11 articles about Benzenecarbothioic acid, O-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

phenylcarbonochloridothioate (1005-56-7) → thiobenzoic acid O-phenyl ester (16911-57-2)

Guidance literature:

In tetrahydrofuran; chlorobenzene;

Reference yield: 34.0%

phenylmagnesium bromide (100-58-3) + phenylcarbonochloridothioate (1005-56-7) → thiobenzoic acid O-phenyl ester (16911-57-2)

Guidance literature:

In tetrahydrofuran; at -78 - 20 ℃; for 3h; Inert atmosphere;

DOI:10.1021/jacs.8b07268

Reference yield:

thiobenzophenone S-oxide (15848-07-4) → benzophenone (119-61-9) + thiobenzoic acid O-phenyl ester (16911-57-2) + phenyl thiobenzoate (884-09-3) + C13H10OS + 2,2-diphenyloxathiirane (60870-95-3)

Guidance literature:

In diethyl ether; ethanol; methylbutane; at -196.1 ℃; Mechanism; Irradiation; magnetic susceptibility measurements variation of wavelength during the reaction;

DOI:10.1016/S0040-4020(01)92060-5

upstream raw materials:

phenyl thiocyanate

thiobenzoic acid

benzoic acid phenyl ester

thiobenzophenone S-oxide

Downstream raw materials:

(benzyloxy)benzene

N-ethylbenzothioamide

N-benzyl-benzenecarbothioamide

2-phenyl-4,5-dihydro-thiazole-4-carboxylic acid methyl ester

Refernces

• 1、 Yang, Eun-Ji,Kim, Min-Young,Um, Ik-Hwan. "Kinetic study on reactions of O-Y-substituted phenyl thionobenzoates with quinuclidine: Factors governing reactivity and reaction mechanism". . p. 1120 - 1125. Retrieved 2015.
• 2、 Yao, Chaochao,Yang, Jinhua,Lu, Xiaobiao,Zhang, Shuyu,Zhao, Junfeng. "Ynamide-Mediated Thionoester and Dithioester Syntheses". . p. 6628 - 6631. Retrieved 2020/09/02.