Mercury, (benzenethiolato)methyl-

Base Information

• Chemical Name: Mercury, (benzenethiolato)methyl-
• CAS No.: 17019-36-2
• Molecular Formula: C7H8HgS
• Molecular Weight: 324.797
• Mol file: 17019-36-2.mol

Synonyms:

Chemical Property of Mercury, (benzenethiolato)methyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mercury, (benzenethiolato)methyl-

There total 23 articles about Mercury, (benzenethiolato)methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

methylmercuric nitrate (2374-27-8) + thiophenol (108-98-5) → (benzenethiolato)methylmercury(II) (17019-36-2)

Guidance literature:

With (C₂H₅)3N; In methanol; under Ar; stirred for 2 h at 25°C; filtration; concentrated; several days at -20°C; crystn.; collected; washed (H2O); elem. anal.; NMR; IR;

Reference yield: 63.0%

sodium thiophenolate (930-69-8) + methylmercury(II) chloride (115-09-3) → (benzenethiolato)methylmercury(II) (17019-36-2)

Guidance literature:

In dichloromethane; (inert atm.); addn. of CH2Cl2 to mixt. of mercury compd. and sodium phenylthiolate, stirring for 2 h; keeping for 30 min, filtration, evapn., NMR and MS;

DOI:10.1021/ic8005426

Reference yield:

methylmercury(II) chloride (115-09-3) + Ph3SnSPh (1441-22-1) → (benzenethiolato)methylmercury(II) (17019-36-2) + triphenyltin chloride (639-58-7)

Guidance literature:

In acetone; equilibrium constant detd.; (199)Hg-NMR and (119)Sn-NMR spectroscopy;

upstream raw materials:

methylmercury(II) bromide

Ph₃SnSPh

methylmercury(II) iodide

methylmercury(II) chloride