Bis(trifluoromethyl) pertrioxide

Base Information

• Chemical Name: Bis(trifluoromethyl) pertrioxide
• CAS No.: 1718-18-9
• Molecular Formula: C2F6O3
• Molecular Weight: 186.011
• Mol file: 1718-18-9.mol

Synonyms:

Chemical Property of Bis(trifluoromethyl) pertrioxide

Chemical Property:

• Boiling Point: -17.08°C (rough estimate)

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Bis(trifluoromethyl) pertrioxide

There total 16 articles about Bis(trifluoromethyl) pertrioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 10.0%

1,1,1-trifluoro-2-propanone (421-50-1) → Carbonyl fluoride (353-50-4) + carbon dioxide (124-38-9,18923-20-1) + Bis(trifluoromethyl)trioxide (1718-18-9) + 3,3,3-Trifluoropyruvaldehyde (91944-47-7)

Guidance literature:

With methylene chloride; chlorine; at 24.85 ℃; under 760 Torr; Kinetics; Photolysis;

DOI:10.1039/b304298g

Reference yield:

bromodifluoromethane (1511-62-2) → carbon tetrafluoride (75-73-0) + Carbonyl fluoride (353-50-4) + Bromotrifluoromethane (75-63-8) + Bis(trifluoromethyl)trioxide (1718-18-9)

Guidance literature:

With fluorine; at 22.9 ℃; Product distribution; Equilibrium constant; Kinetics; Irradiation; also in the presence CH₄;

DOI:10.1021/jp9530111

Reference yield:

1,1,1,3,3-Pentafluoropropane (460-73-1) → 2,2,2-Trifluoroacetaldehyde (75-90-1) + Bis(trifluoromethyl)trioxide (1718-18-9) + trifluoroacetic acid (76-05-1)

Guidance literature:

With oxygen; chlorine; at 23.9 ℃; under 700 Torr; Rate constant; Irradiation;

DOI:10.1021/jp963735s

upstream raw materials:

1,1,1,2-tetrafluoroethane

1,1,1,4,4,4-hexafluoro-2,3-bis-trifluoromethyl-but-2-ene

Hexafluoroacetone

trifluoroacetic acid

Refernces

• 1、 Hasson, Alam S.,Moore, Christopher M.,Smith, Ian W. M.. "Fluorine-atom initiated oxidation of CF3CF2H (HFC-125) studied by FTIR spectroscopy: Product yields and kinetic modelling". . p. 2693 - 2699. Retrieved 1997.
• 2、 Louis, Florent,Burgess Jr., Donald R.,Rayez, Marie-Therese,Sawerysyn, Jean-Pierre. "Kinetic study of the reactions of CF3O2 radicals with Cl and NO". . p. 5087 - 5096. Retrieved 1999.
• 3、 Carr, Sinead,Shallcross, Dudley E.,Canosa-Mas, Carlos E.,Wenger, John C.,Sidebottom, Howard W.,Treacy, Jack J.,Wayne, Richard P.. "A kinetic and mechanistic study of the gas-phase reactions of OH radicals and Cl atoms with some halogenated acetones and their atmospheric implications". . p. 3874 - 3883. Retrieved 2007/10/03.