9(10H)-Anthracenone, 1,8-bis(acetyloxy)-

Base Information

• Chemical Name: 9(10H)-Anthracenone, 1,8-bis(acetyloxy)-
• CAS No.: 38165-75-2
• Molecular Formula: C18H14 O5
• Molecular Weight: 310.306
• DSSTox Substance ID: DTXSID70191550
• Wikidata: Q83064077
• Mol file: 38165-75-2.mol

Synonyms:9(10H)-Anthracenone, 1,8-bis(acetyloxy)-;38165-75-2;DTXSID70191550

Chemical Property of 9(10H)-Anthracenone, 1,8-bis(acetyloxy)-

Chemical Property:

• XLogP3: 2.3
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 310.08412354
• Heavy Atom Count: 23
• Complexity: 458

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C2=C(C(=CC=C2)CC(=O)O)C(=O)C3=C1C=CC=C3CC(=O)O

Technology Process of 9(10H)-Anthracenone, 1,8-bis(acetyloxy)-

There total 1 articles about 9(10H)-Anthracenone, 1,8-bis(acetyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

1,8-dihydroxy-9(10H)-anthracenone (1143-38-0) + acetyl chloride (75-36-5) → 1-acetyloxy-9(10H)-anthracenone (2891-34-1) + 1,8-diacetyloxy-9(10H)-anthracenone (38165-75-2) + 1,8,9-triacetyloxyanthracene (16203-97-7) + 10-acetyl-1,8,9-triacetoxy anthracene (3360-93-8)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 20 ℃; for 0.333333h; Product distribution;

DOI:10.1002/jccs.200400018

Reference yield: 39.0%

1,8-diacetyloxy-9(10H)-anthracenone (38165-75-2) + 4-methoxy-benzoyl chloride (100-07-2) → 1,8-diacetoxy-10-[(4-methoxybenzoyloxy)-4-methoxyphenylmethylene]-9(10H)-anthracenone (209347-43-3)

Guidance literature:

With sodium hydride; In tetrahydrofuran; for 1h; Ambient temperature;

DOI:10.1016/S0223-5234(98)80010-X

Reference yield: 37.0%

3,4-(diacetyloxy)benzoyl chloride (57929-25-6) + 1,8-diacetyloxy-9(10H)-anthracenone (38165-75-2) → 1,8-diacetoxy-10-[(3,4-diacetoxybenzoyloxy)-3,4-diacetoxyphenylmethylene]-9(10H)-anthracenone

Guidance literature:

With sodium hydride; In tetrahydrofuran; for 1h; Ambient temperature;

DOI:10.1016/S0223-5234(98)80010-X

upstream raw materials:

1,8-dihydroxy-9(10H)-anthracenone

acetyl chloride

Downstream raw materials:

10-bromo-1,8-dihydroxy-9(10H)-anthracenone

1,8-diacetoxy-10-[(4-benzyloxybenzoyloxy)-4-benzyloxyphenylmethylene]-9(10H)-anthracenone

1,8-diacetoxy-10-[(4-propoxybenzoyloxy)-4-propoxyphenylmethylene]-9(10H)-anthracenone

1,8-diacetoxy-10-[(4-methoxybenzoyloxy)-4-methoxyphenylmethylene]-9(10H)-anthracenone