Tetraethylammonium bicarbonate

Base Information

• Chemical Name: Tetraethylammonium bicarbonate
• CAS No.: 17351-61-0
• Molecular Formula: C8H20N.CHO3
• Molecular Weight: 191.271
• European Community (EC) Number: 629-539-5
• DSSTox Substance ID: DTXSID10473089
• Mol file: 17351-61-0.mol

Synonyms:TETRAETHYLAMMONIUM BICARBONATE;17351-61-0;tetraethylammonium hydrogencarbonate;hydrogen carbonate;tetraethylazanium;Ethanaminium, N,N,N-triethyl-, carbonate (1:1);tetraethylazanium hydrogen carbonate;Tetraethylammonium hydrogen carbonate;SCHEMBL405573;DTXSID10473089;tetraethylammoniumhydrogencarbonate;XUBMPLUQNSSFHO-UHFFFAOYSA-M;AKOS030529055;AS-67201;CS-0160244;D94554

Chemical Property of Tetraethylammonium bicarbonate

Chemical Property:

• PSA: 60.36000
• LogP: 0.77050
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 191.15214353
• Heavy Atom Count: 13
• Complexity: 72.2

Purity/Quality:

97% ^*data from raw suppliers

Tetraethylammonium bicarbonate ≥95.0%(T) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[N+](CC)(CC)CC.C(=O)(O)[O-]
• Uses: Tetraethylammonium bicarbonate is used:In the synthesis of carbamate esters from amines.As a precipitant for synthesizing Cu/ZnO catalysts via coprecipitation method.As an alternative to the traditional phase-transfer system in [18F]radiofluorinations for preventing microreactor blockages.To promote carboxylation of secondary carboxamides bearing a leaving group at the α-position in the synthesis of oxazolidine-2,4-diones.

Technology Process of Tetraethylammonium bicarbonate

There total 11 articles about Tetraethylammonium bicarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Diethyl carbonate (105-58-8,76619-83-5) → tetraethylammonium hydroxide (77-98-5) + tetraethylammonium bicarbonate (17351-61-0)

Guidance literature:

With triethylamine; In water;

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + tetraethylammonium hydroxide (77-98-5) → tetraethylammonium bicarbonate (17351-61-0)

Guidance literature:

In water;

DOI:10.1007/s10562-013-1088-1

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + tetraethylammonium chloride (56-34-8) → tetraethylammonium bicarbonate (17351-61-0)

Guidance literature:

tetraethylammonium chloride; With potassium hydroxide; In methanol;

carbon dioxide; In methanol; at 20 ℃; for 2h;

upstream raw materials:

Diethyl carbonate

carbon dioxide

tetraethylammonium hydroxide

tetraethylammonium chloride

Downstream raw materials:

dimethylenecyclourethane

benzyl N-cyclohexylcarbamate

ethyl N-cyclohexylcarbamate

cyclohexylcarbamic acid isopropyl ester