[(cyclopentadienyl)Co((NH)S(C₆H₂FNO₂))]

Base Information

• Chemical Name: [(cyclopentadienyl)Co((NH)S(C₆H₂FNO₂))]
• CAS No.: 620178-78-1
• Molecular Formula: C₁₁H₈CoFN₂O₂S
• Molecular Weight: 310.254
• Mol file: 620178-78-1.mol

Synonyms:

Chemical Property of [(cyclopentadienyl)Co((NH)S(C₆H₂FNO₂))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(cyclopentadienyl)Co((NH)S(C₆H₂FNO₂))]

There total 4 articles about [(cyclopentadienyl)Co((NH)S(C₆H₂FNO₂))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.0%

{(η-cyclopentadienyl)(1,2-dicyano-1,2-ethylenedithiolato)cobalt(III)} (12082-04-1) + 4-fluoro-3-nitrophenyl azide → [(cyclopentadienyl)Co((NH)S(C6H2FNO2))] (620178-78-1) + [(cyclopentadienyl)Co((N(3-fluoro-4-nitrophenyl))SC2(CN)2)] + [(cyclopentadienyl)Co((N(3-fluoro-4-nitrophenyl))2C2(CN)2)]

Guidance literature:

In xylene; under Ar; soln. of CpCoS2C2(CN)2 and 3-fluoro-4-nitrophenyl azide (5 equiv) in xylene refluxed for 24 h; solvent removed under reduced pressure; residue sepd. by thin-layer chromy. (silica gel 60); product further sepd. by HPLC; HR-Mass anal.;

DOI:10.1016/S0022-328X(03)00599-0

Reference yield: 7.0%

[(cyclopentadienyl)Co(S2C2Me2)] (161206-13-9) + 4-fluoro-3-nitrophenyl azide → [(cyclopentadienyl)Co((NH)S(C6H2FNO2))] (620178-78-1) + [(cyclopentadienyl)Co((N(3-fluoro-4-nitrophenyl))SC2Me2)] + [(cyclopentadienyl)Co((N(3-fluoro-4-nitrophenyl))2C2Me2)]

Guidance literature:

In xylene; under Ar; soln. of CpCoS2C2Me2 and 3-fluoro-4-nitrophenyl azide (5 equiv) in xylene refluxed for 24 h; solvent removed under reduced pressure; residue sepd. by thin-layer chromy. (silica gel 60); product further sepd. by HPLC; HR-Mass anal.;

DOI:10.1016/S0022-328X(03)00599-0

Reference yield: 6.0%

(η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III) (86543-64-8) + 4-fluoro-3-nitrophenyl azide → [(cyclopentadienyl)Co((NH)S(C6H2FNO2))] (620178-78-1) + [(cyclopentadienyl)Co((N(3-fluoro-4-nitrophenyl))SC2Ph2)] + [(cyclopentadienyl)Co((N(3-fluoro-4-nitrophenyl))2C2Ph2)]

Guidance literature:

In xylene; under Ar; soln. of CpCoS2C2Ph2 and 3-fluoro-4-nitrophenyl azide (5 equiv) in xylene refluxed for 24 h; solvent removed under reduced pressure; residue sepd. by thin-layer chromy. (silica gel 60); product further sepd. by HPLC; HR-Mass anal.;

DOI:10.1016/S0022-328X(03)00599-0

upstream raw materials:

[(cyclopentadienyl)Co(S₂C₂Me₂)]

{(η-cyclopentadienyl)(1,2-dicyano-1,2-ethylenedithiolato)cobalt(III)}

(η(5)-cyclopentadienyl)[1,2-bis(methoxycarbonyl)ethenethiolato-κS]cobalt(III)

(η-cyclopentadienyl)(1,2-diphenyl-1,2-ethylenedithiolato)cobalt(III)