Dicyclopentylmethanone

Base Information

• Chemical Name: Dicyclopentylmethanone
• CAS No.: 17610-48-9
• Molecular Formula: C11H18O
• Molecular Weight: 166.263
• DSSTox Substance ID: DTXSID10396825
• Nikkaji Number: J980.525G
• Wikidata: Q82197740
• Mol file: 17610-48-9.mol

Synonyms:dicyclopentylmethanone;17610-48-9;dicyclopentyl ketone;CHEMBRDG-BB 5100809;dicyclopentyl-methanone;SCHEMBL289269;DTXSID10396825;NWDXDEBDJICFAS-UHFFFAOYSA-N;MFCD00540242;AKOS010145130;BS-35783;CS-0448326;EN300-253223;Z608405422

Chemical Property of Dicyclopentylmethanone

Chemical Property:

• Vapor Pressure: 0.0399mmHg at 25°C
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 166.135765193
• Heavy Atom Count: 12
• Complexity: 144

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(C1)C(=O)C2CCCC2

Technology Process of Dicyclopentylmethanone

There total 2 articles about Dicyclopentylmethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-benzoylpyrrolidine-2,5-dione (6343-27-7) + Cyclopentane (287-92-3) → dicyclopentyl ketone (17610-48-9) + phenyl cyclopentyl ketone (5422-88-8)

Guidance literature:

With potassium phosphate; sodium tungstate (VI) dihydrate; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate; tetraaqua[4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]nickel(II) chloride; lithium chloride; In benzene; at 20 ℃; for 24h; Overall yield = 53 percent; Overall yield = 0.066 g; Inert atmosphere; Sealed tube; Schlenk technique; Irradiation;

DOI:10.1055/s-0040-1707301

Reference yield:

carbon monoxide (201230-82-2) + cyclopentene (142-29-0) → cyclopentanealdehyde (872-53-7) + dicyclopentyl ketone (17610-48-9) + cyclopent-1-en-1-yl cyclopentyl ketone (61784-26-7) + Cyclopent-2-enyl-cyclopentyl-methanone

Guidance literature:

With hydrogen; (dpp)Pd(OTf)2; In various solvent(s); at 110 ℃; for 20h; under 60004.8 Torr; Product distribution; other catalysts; also in the presence of various N,N'-disubstituted urea derivatives;

DOI:10.1039/a806722h

Reference yield:

cis-Re2(O2CEt)2Cl2(μ2-dppm)2 + dicyclopentyl ketone (17610-48-9) → cis-dirhenium(μ-S2C(cyclopentyl)2)(Cl)2(μ-Ph2PCH2PPh2)2

Guidance literature:

With HBF₄*Et₂O; H₂S; In further solvent(s); byproducts: EtCO2H, H2O; elem. anal.;

DOI:10.1039/c39920000375

upstream raw materials:

carbon monoxide

cyclopentene

1-benzoylpyrrolidine-2,5-dione

Cyclopentane