4-Methylcyclohexanone dimethyl acetal

Base Information

• Chemical Name: 4-Methylcyclohexanone dimethyl acetal
• CAS No.: 18349-20-7
• Molecular Formula: C9H18O2
• Molecular Weight: 158.241
• Mol file: 18349-20-7.mol

Synonyms:1,1-dimethoxy-4-methyl-cyclohexane;1,1-dimethoxy-4-methylcyclohexane;4-methyl-cyclohexanone dimethyl acetal;4-Methyl-cyclohexanon-dimethylacetal;4-Methyl-cyclohexanon-dimethylketal;4-Methylcyclohexanone dimethyl acetal;

Chemical Property of 4-Methylcyclohexanone dimethyl acetal

Chemical Property:

• Boiling Point: 177.8±13.0 °C(Predicted)
• PSA: 18.46000
• Density: 0.91±0.1 g/cm3(Predicted)
• LogP: 2.18560

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-Methylcyclohexanone dimethyl acetal

There total 4 articles about 4-Methylcyclohexanone dimethyl acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

methanol (67-56-1) + 1-methylcyclohexan-4-one (589-92-4) → 4-methylcyclohexanone dimethyl acetal (18349-20-7)

Guidance literature:

Ce⁽³⁺⁾-mont; at 25 ℃; for 0.5h;

DOI:10.1021/jo00118a021

Reference yield: 15.0%

methanol (67-56-1) + 1-methylcyclohexan-4-one (589-92-4) → 4-methylcyclohexanone dimethyl acetal (18349-20-7) + trans-4-methylcyclohexan-1-ol (7731-29-5) + cis-4-methylcyclohexanol (7731-28-4)

Guidance literature:

With sodium hydroxide; N,N'-di(4-bromophenyl)-N,N'-dimethylethylenediamine; hydrogen; [Ir(1,5-cyclooctadiene)2]PF₆; at 50 ℃; for 21h; under 34200 Torr;

DOI:10.1021/jo020506v

Reference yield:

1-methylcyclohexan-4-one (589-92-4) + trimethyl orthoformate (149-73-5) → 4-methylcyclohexanone dimethyl acetal (18349-20-7)

Guidance literature:

With toluene-4-sulfonic acid; In methanol; Heating;

DOI:10.1055/s-1986-31492

upstream raw materials:

1-methylcyclohexan-4-one

trimethyl orthoformate

methanol

Downstream raw materials:

1-methylcyclohexan-4-one

1,1-Dibromo-4-methyl-cyclohexane

1-bromo-4-methyl-1-cyclohexene

4-methylcyclohexane-1,1-diyl dihydroperoxide