2,4-Pentanedione, 3-(acetyloxy)-

Base Information

• Chemical Name: 2,4-Pentanedione, 3-(acetyloxy)-
• CAS No.: 18632-38-7
• Molecular Formula: C7H10O4
• Molecular Weight: 158.154
• Mol file: 18632-38-7.mol

Synonyms:3-acetoxypentan-2,4-dione;3-(acetoxy)acetylacetone;3-acetoxyacetylacetone;3-acetoxypentane-2,4-dione;3-acetoxy-2,4-pentanedione;HacacOC(O)CH3;

Chemical Property of 2,4-Pentanedione, 3-(acetyloxy)-

Chemical Property:

• PSA: 60.44000
• LogP: 0.09610

Purity/Quality:

95+% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: 3-?(Acetyloxy)?-2,?4-?pentanedione is an intermediate in the synthesis of N5-(5-Hydroxy-4,6-dimethyl-2-pyrimidinyl)-L-ornithine Hydrochloride Hydrate (H825805) which is an advanced glycation end-products with an antiglycation potential.

Technology Process of 2,4-Pentanedione, 3-(acetyloxy)-

There total 1 articles about 2,4-Pentanedione, 3-(acetyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

lead(IV) tetraacetate (546-67-8) + acetylacetone (123-54-6,81235-32-7) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 1,1,2,2-Tetraacetylethan (5027-32-7) + 3-acetoxypentane-2,4-dione (18632-38-7)

Guidance literature:

DOI:10.1039/jr9550004426

Reference yield: 99.0%

4H-1,3-benzodioxin-2-one (112055-31-9) + 3-acetoxypentane-2,4-dione (18632-38-7) → C14H16O5

Guidance literature:

With Adipic acid; allyl(cyclopentadiene)palladium(II); C₁₀H₂₄N₂*C₂HF₆NO₄S₂; tricyclohexylphosphine; In tetrahydrofuran; acetonitrile; at 60 ℃; for 48h; enantioselective reaction; Inert atmosphere;

DOI:10.1021/acs.orglett.9b02491

Reference yield: 99.0%

titanium(IV)isopropoxide (546-68-9) + 3-acetoxypentane-2,4-dione (18632-38-7) → C20H32O10Ti

Guidance literature:

In hexane; at 20 ℃;

DOI:10.1002/ejic.202100209

upstream raw materials:

lead(IV) tetraacetate

acetylacetone

benzene

Downstream raw materials:

4-hydroxy-pentane-2,3-dione enediol tautomer

6-Phenyl-6-hydroxy-3-acetoxy-2,4-dioxo-hexan

3,5-dimethylisoxazol-4-ol

2-(dimethylamino)-4,6-dimethyl-5-pyrimidinol