10H-Phenothiazine, 10-(4-nitrophenyl)-

Base Information

• Chemical Name: 10H-Phenothiazine, 10-(4-nitrophenyl)-
• CAS No.: 19606-94-1
• Molecular Formula: C18H12N2O2S
• Molecular Weight: 320.371
• Mol file: 19606-94-1.mol

Synonyms:10-(p-Nitrophenyl)phenothiazine;10-(4-nitro-phenyl)-phenothiazine;10-(4-Nitro-phenyl)-phenothiazin;10-(4-nitro-phenyl)-10H-phenothiazine;N-(p-nitrophenyl)phenothiazine;10H-Phenothiazine,10-(4-nitrophenyl);4'-nitro-10-phenylphenothiazine;N-(4-nitrophenyl)phenothiazine;

Chemical Property of 10H-Phenothiazine, 10-(4-nitrophenyl)-

Chemical Property:

• PSA: 74.36000
• LogP: 6.11740

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10H-Phenothiazine, 10-(4-nitrophenyl)-

There total 4 articles about 10H-Phenothiazine, 10-(4-nitrophenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

phenothiazine nitranion (76069-04-0) + 4-chlorobenzonitrile (100-00-5) → 10-(4-nitrophenyl)-10-H-phenothiazine (19606-94-1)

Guidance literature:

In dimethyl sulfoxide; at 25 ℃; Rate constant; Mechanism;

DOI:10.1021/ja00279a054

Reference yield: 91.0%

10H-phenothiazine (92-84-2) + 4-Fluoronitrobenzene (350-46-9,178603-76-4) → 10-(4-nitrophenyl)-10-H-phenothiazine (19606-94-1)

Guidance literature:

With cesium fluoride; In dimethyl sulfoxide; at 120 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c0jm01889a

Reference yield: 75.8%

p-nitrobenzene iodide (636-98-6) + 10H-phenothiazine (92-84-2) → 10-(4-nitrophenyl)-10-H-phenothiazine (19606-94-1)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium tert-butylate; tris-(o-tolyl)phosphine; In toluene; at 90 ℃; for 24h;

DOI:10.1021/ja0398215

upstream raw materials:

phenothiazine nitranion

4-chlorobenzonitrile

p-nitrobenzene iodide

10H-phenothiazine

Downstream raw materials:

10-(4-aminophenyl)-10-H-phenothiazine

4,4'-diamino-4''-N-phenothiazinyltriphenylamine

N-(4-(10H-phenothiazin-10-yl)phenyl)acetamide

Refernces

• 1、 Damaceanu, Mariana-Dana,Constantin, Catalin-Paul,Bejan, Andra-Elena,Mihaila, Mihai,Kusko, Mihaela,Diaconu, Cristian,Mihalache, Iuliana,Pascu, Razvan. "Heteroatom-mediated performance of dye-sensitized solar cells based on T-shaped molecules". . p. 15 - 31. Retrieved 2019/03/14.
• 2、 Chen, Mao,Deng, Shihong,Gu, Yuwei,Lin, Jun,MacLeod, Michelle J.,Johnson, Jeremiah A.. "Logic-Controlled Radical Polymerization with Heat and Light: Multiple-Stimuli Switching of Polymer Chain Growth via a Recyclable, Thermally Responsive Gel Photoredox Catalyst". supporting information. p. 2257 - 2266. Retrieved 2017/02/23.