1H-Imidazole, 1-methyl-2-[(4-methylphenyl)azo]-

Base Information

• Chemical Name: 1H-Imidazole, 1-methyl-2-[(4-methylphenyl)azo]-
• CAS No.: 198347-67-0
• Molecular Formula: C11H12N4
• Molecular Weight: 200.243
• DSSTox Substance ID: DTXSID90406911
• Nikkaji Number: J1.058.596A,J3.123.065I
• Mol file: 198347-67-0.mol

Synonyms:1H-Imidazole, 1-methyl-2-[(4-methylphenyl)azo]-;198347-67-0;SCHEMBL13785578;DTXSID90406911;1-methyl-2-(p-tolylazo)imidazole

Chemical Property of 1H-Imidazole, 1-methyl-2-[(4-methylphenyl)azo]-

Chemical Property:

• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 200.106196400
• Heavy Atom Count: 15
• Complexity: 221

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)N=NC2=NC=CN2C

Technology Process of 1H-Imidazole, 1-methyl-2-[(4-methylphenyl)azo]-

There total 2 articles about 1H-Imidazole, 1-methyl-2-[(4-methylphenyl)azo]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-methyl-2-(phenylazo)imidazole (34938-48-2) + methyl iodide (74-88-4) → 1-methyl-2-(4'-methylphenylazo)imidazole (198347-67-0)

Guidance literature:

With sodium hydride; In tetrahydrofuran; Reflux;

Reference yield:

→ 1-methyl-2-(4'-methylphenylazo)imidazole (198347-67-0)

Guidance literature:

1) 2(p-Tolylazo)imidazol, NaNH2 2) Methyljodid;

Reference yield: 84.0%

rhenium(I) pentacarbonyl chloride (14099-01-5) + 1-methyl-2-(4'-methylphenylazo)imidazole (198347-67-0) → chloro(2-(p-tolylazo)-1-methylimidazole)tricarbonylrhenium(I) (711011-88-0)

Guidance literature:

In benzene; byproducts: CO; ligand (1.2 equiv.) added to hot soln. of Re complex in benzene; heated to reflux for 3 h; solvent evapd. under reduced pressure; washed with hexane; dried; recrystd. from CH2Cl2-hexane; dried in vac. over fused CaCl2; elem. anal.;

DOI:10.1016/j.jorganchem.2004.02.034

upstream raw materials:

1-methyl-2-(phenylazo)imidazole

methyl iodide

Downstream raw materials:

dichloro(1-methyl-2-(p-tolylazo)imidazole)platinum(II)

trans-cis-cis-Ru(1-methyl-2-(4'-methylphenylazo)imidazole)2Cl₂

di-thiocyanato-bis[1-methyl-2-(p-tolylazo)imidazole]zinc(II)

[bis(1-methyl-2-(p-tolylazo)imidazole)dichlorocadmium(II)]