bromo[2'-(1''-phenyl-5'',6''-dihydropyrrolo[2,1-a]isoquinolin-3''-ylcarbonyloxy)phenyl]bis(triphenylphosphine)palladium

Base Information

Chemical Name:bromo[2'-(1''-phenyl-5'',6''-dihydropyrrolo[2,1-a]isoquinolin-3''-ylcarbonyloxy)phenyl]bis(triphenylphosphine)palladium
CAS No.:252881-65-5
Molecular Formula:C₆₁H₄₈BrNO₂P₂Pd
Molecular Weight:1075.33
Hs Code.:

Synonyms:

Suppliers and Price of bromo[2'-(1''-phenyl-5'',6''-dihydropyrrolo[2,1-a]isoquinolin-3''-ylcarbonyloxy)phenyl]bis(triphenylphosphine)palladium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of bromo[2'-(1''-phenyl-5'',6''-dihydropyrrolo[2,1-a]isoquinolin-3''-ylcarbonyloxy)phenyl]bis(triphenylphosphine)palladium

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of bromo[2'-(1''-phenyl-5'',6''-dihydropyrrolo[2,1-a]isoquinolin-3''-ylcarbonyloxy)phenyl]bis(triphenylphosphine)palladium

There total 1 articles about bromo[2'-(1''-phenyl-5'',6''-dihydropyrrolo[2,1-a]isoquinolin-3''-ylcarbonyloxy)phenyl]bis(triphenylphosphine)palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.5%

: 127-09-3
sodium acetate

: 3375-31-3
palladium diacetate

: 603-35-0
triphenylphosphine

: 252861-21-5
2-bromophenyl 1-[2'-(2''-bromophenyl)ethyl]-4-phenylpyrrole-2-carboxylate

: 252881-65-5
bromo[2'-(1''-phenyl-5'',6''-dihydropyrrolo[2,1-a]isoquinolin-3''-ylcarbonyloxy)phenyl]bis(triphenylphosphine)palladium

Guidance literature:: In N,N-dimethyl-formamide; byproducts: C25H18BrNO2; N2 atmosphere; heating (110°C, 19 h); cooling, diln. (EtOAc), washing (brine, H2O), drying org. phase (MgSO4),filtration, concn. (reduced pressure), flash chromy. (silica/CH2Cl2/hex ane = 1 : 2, then 1 : 1), elution (CH2Cl2/EtOAc = 4 : 1), concn. of 2nd.fraction, CH2Cl2 elution;
DOI:10.1071/CH99021