tert-butyl ethane(dithioperoxo)oate

Base Information

• Chemical Name: tert-butyl ethane(dithioperoxo)oate
• CAS No.: 31172-01-7
• Molecular Formula: C₆H₁₂OS₂
• Molecular Weight: 164.293
• Mol file: 31172-01-7.mol

Synonyms:Peroxyaceticacid, dithio-, SS-tert-butyl ester (8CI); NSC 329618

Chemical Property of tert-butyl ethane(dithioperoxo)oate

Chemical Property:

• Vapor Pressure: 0.0928mmHg at 25°C
• Boiling Point: 224.1°C at 760 mmHg
• Flash Point: 84.1°C
• Density: 1.076g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tert-butyl ethane(dithioperoxo)oate

There total 3 articles about tert-butyl ethane(dithioperoxo)oate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

tert-butyl tert-butanethiosulfinate (31562-40-0) + tiolacetic acid (507-09-5) → acetyl t-butyl disulfide (31172-01-7)

Guidance literature:

With triethylamine; In dichloromethane; for 48h; Ambient temperature;

DOI:10.1055/s-1994-25551

Reference yield:

acetyl-chloro-sulfane (6405-82-9) + 2-methylpropan-2-thiol (75-66-1) → acetyl t-butyl disulfide (31172-01-7)

Guidance literature:

In diethyl ether;

DOI:10.1021/jo01318a019

Reference yield:

di-tert-butyl disulfide (110-06-5) + tiolacetic acid (507-09-5) → acetyl t-butyl disulfide (31172-01-7)

Guidance literature:

Multistep reaction; (i) Cl₂, CH₂Cl₂, (ii) /BRN= 773684/;

DOI:10.1021/jm00285a006

upstream raw materials:

acetyl-chloro-sulfane

2-methylpropan-2-thiol

di-tert-butyl disulfide

tiolacetic acid