Methyl tetradecanoate

Base Information

• Chemical Name: Methyl tetradecanoate
• CAS No.: 124-10-7
• Molecular Formula: C15H30O2
• Molecular Weight: 242.402
• Hs Code.: 2915900090
• European Community (EC) Number: 204-680-1
• NSC Number: 5029
• UNII: RG9851783C
• DSSTox Substance ID: DTXSID5027019
• Nikkaji Number: J382D
• Wikidata: Q27161384
• Metabolomics Workbench ID: 4112
• ChEMBL ID: CHEMBL207549
• Mol file: 124-10-7.mol

Synonyms:C14-MES;methyl tetradecanoate;tetradecanoic acid methyl ester;tetradecanoic acid methyl ester sodium salt

Chemical Property of Methyl tetradecanoate

Chemical Property:

• Appearance/Colour: clear colorless to yellowish liquid
• Melting Point: 18 °C(lit.)
• Refractive Index: n20/D 1.436(lit.)
• Boiling Point: 323 °C at 760 mmHg
• Flash Point: 134.6 °C
• PSA: 26.30000
• Density: 0.866 g/cm³
• LogP: 4.86050
• XLogP3: 6.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 13
• Exact Mass: 242.224580195
• Heavy Atom Count: 17
• Complexity: 166

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Safety Statements: S24/25:Avoid contact with skin and eyes.

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Uses -> Emulsifiers/Surfactants
• Canonical SMILES: CCCCCCCCCCCCCC(=O)OC

Technology Process of Methyl tetradecanoate

There total 52 articles about Methyl tetradecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

n-tetradecanoic acid (544-63-8) + methyl salicylate (119-36-8,8024-54-2) → methyl myristoate (124-10-7) + salicylic acid (69-72-7,25496-36-0,8052-31-1)

Guidance literature:

n-tetradecanoic acid; With potassium carbonate; In N,N-dimethyl acetamide; at 110 ℃; for 0.5h;

methyl salicylate; at 110 ℃; for 24h;

DOI:10.1055/s-0033-1340285

Reference yield:

methanol (67-56-1) → methyl (7Z,10Z,13Z,16Z,19Z)-docosa-7,10,13,16,19-pentaenoate (108698-02-8) + methyl vaccenate (1937-63-9,52380-33-3,6198-58-9) + methyl linoleate (16326-32-2) + methyl arachidonate (2566-89-4) + (Z)-9-hexadecenoic acid methyl ester (1120-25-8,3913-63-1) + Methyl oleate (112-62-9) + Methyl linoleate (112-63-0) + (11Z)-11-icosenoic acid methyl ester (2390-09-2,3946-08-5) + methyl linolenate (301-00-8) + methyl n-dodecanoate (111-82-0) + methyl myristoate (124-10-7) + pentadecanoic acid methyl ester (7132-64-1) + hexadecanoic acid methyl ester (112-39-0) + methyl margarate (1731-92-6) + Methyl stearate (112-61-8) + methyl arachidate (1120-28-1) + behenic acid methyl ester (929-77-1) + all-cis-8,11,14-eicosatrienoic acid methyl ester (21061-10-9) + (5Z,8Z,11Z,14Z,17Z)-5,8,11,14,17-icosapentaenoic acid methyl ester (2734-47-6) + cis,cis,cis,cis-Docosa-7,10,13,16-tetraensaeuremethylester (13487-42-8) + myristoleic acid methyl ester (56219-06-8) + cis,trans-9,11-methyloctadecadienoate (35042-75-2)

Guidance literature:

With potassium hydroxide; water; In methanol; at 55 ℃; for 1.5h;

methanol; With sulfuric acid; In water; at 20 - 55 ℃; for 1.5h; Product distribution / selectivity;

Reference yield:

methanol (67-56-1) + soybean oil (8001-22-7) → methyl trans-2-octadecenoate (14663-11-7) + 5,8,11-Eicosatrienoic acid, methyl ester + heneicosapentaenoic acid methyl ester + eicosadienoic acid methyl ester (88400-02-6) + docosapentaenoic acid methyl ester + docosatetraenoic acid methyl ester + docosadienoic acid methyl ester + palmitelaidic acid methyl ester (10030-74-7,3913-63-1) + Methyl oleate (112-62-9) + Methyl linoleate (112-63-0) + methyl cis-13-docosenoate (1120-34-9) + methyl cis-tetracos-15-enate (2733-88-2) + methyl myristoate (124-10-7) + hexadecanoic acid methyl ester (112-39-0) + methyl margarate (1731-92-6) + Methyl stearate (112-61-8) + methyl arachidate (1120-28-1) + behenic acid methyl ester (929-77-1) + methyl tetracosanoate (2442-49-1) + methyl (2E)-eicosenoate (10305-59-6) + methyl (9Z,12Z,15E)-octadeca-9,12,15-trienoate (37929-05-8) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0)

Guidance literature:

With potassium hydroxide; at 48 - 52 ℃; for 4h;

upstream raw materials:

methanol

n-tetradecanoic acid

diazomethane

3-carbonyloxypropyonyl dodecanoyl peroxide

Downstream raw materials:

9-Octyl-docosan

1-Tetradecanol

heptacosan-14-one

myristic monoethanolamide

Refernces

• 1、 Tsuda, Yoshisuke,Yoshimoto, Kimihiro. "General path of O-acyl migration in D-glucose derivatives". . p. C1 - C4. Retrieved 1981.
• 2、 Al-Lihaibi, Sultan Samran,Ayyad, Seif-Eldin Nasr,Shaher, Fekry,Alarif, Walied Mohamed. "Antibacterial sphingolipid and steroids from the black coral Antipathes dichotoma". . p. 1635 - 1638. Retrieved 2010.
• 3、 -. "Preparation method of carboxylic ester compound". Paragraph 0034-0035. . Retrieved 2021/03/30.
• 4、 Ho, Wen-Yueh,Lin, Wesley,Lin, Yi-Jyun,Luo, Shun-Yuan,Pantawane, Amit,Su, Po-Fang,Thul, Mayur,Tseng, Shao-An,Wu, Hsin-Ru. "Tunable aryl imidazolium ionic liquids (TAIILs) as environmentally benign catalysts for the esterification of fatty acids to biodiesel fuel". . . Retrieved 2020/12/02.