Ethyl 4-bromo-2-methylbutanoate

Base Information

Chemical Name:Ethyl 4-bromo-2-methylbutanoate
CAS No.:2213-09-4
Molecular Formula:C7H13BrO2
Molecular Weight:209.083
Hs Code.:2915900090
DSSTox Substance ID:DTXSID10509690
Mol file:2213-09-4.mol

Synonyms:ethyl 4-bromo-2-methylbutanoate;2213-09-4;butanoic acid, 4-bromo-2-methyl-, ethyl ester;ethyl4-bromo-2-methylbutanoate;ethyl 4-bromo-2-methylbutyrate;SCHEMBL1896664;3-(ethoxycarbonyl)butyl bromide;DTXSID10509690;FYLONIWABFGHJB-UHFFFAOYSA-N;ethyl gamma-bromo-alpha-methylbutyrate;4-bromo-2-methyl-butyric acid ethyl ester;FT-0724711

Suppliers and Price of Ethyl 4-bromo-2-methylbutanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Ethyl 4-bromo-2-methylbutanoate

Chemical Property:

PSA：26.30000
LogP:1.97060
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:208.00989
Heavy Atom Count:10
Complexity:104

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)C(C)CCBr

Technology Process of Ethyl 4-bromo-2-methylbutanoate

There total 5 articles about Ethyl 4-bromo-2-methylbutanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 64-17-5
ethanol

: 1679-47-6
3-methyltetrahydro-2-furanone

: 2213-09-4
4-bromo-2-methylbutanoic acid ethyl ester

Guidance literature:: With hydrogen bromide; for 72h; Ambient temperature;
DOI:10.1021/jo952053i

Reference yield: 7.3%

: 80566-57-0
4-hydroxy-2-methylbutyric acid ethyl ester

: 2213-09-4
4-bromo-2-methylbutanoic acid ethyl ester

Guidance literature:: With pyridine; N-Bromosuccinimide; triphenylphosphine; In dichloromethane; for 16h;

Reference yield:

: 21382-82-1
(carbethoxyethylidene)triphenylphosphorane

: 2213-09-4
4-bromo-2-methylbutanoic acid ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: benzene / 16 h / 70 °C

2: palladium 10% on activated carbon; hydrogen / methanol; ethyl acetate / 12 h / 20 °C

3: N-Bromosuccinimide; triphenylphosphine; pyridine / dichloromethane / 16 h

With pyridine; N-Bromosuccinimide; palladium 10% on activated carbon; hydrogen; triphenylphosphine; In methanol; dichloromethane; ethyl acetate; benzene;