Bromomethyl-dimethyl-phenylsilane

Base Information

• Chemical Name: Bromomethyl-dimethyl-phenylsilane
• CAS No.: 22655-93-2
• Molecular Formula: C9H13BrSi
• Molecular Weight: 229.192
• DSSTox Substance ID: DTXSID90503934
• Wikidata: Q82358068
• Mol file: 22655-93-2.mol

Synonyms:22655-93-2;Bromomethyl-dimethyl-phenylsilane;(BROMOMETHYL)DIMETHYLPHENYLSILANE;SCHEMBL9712158;bromomethyl(dimethyl)phenylsilane;DTXSID90503934;(Bromomethyl)(dimethyl)phenylsilane;MFCD03412138

Chemical Property of Bromomethyl-dimethyl-phenylsilane

Chemical Property:

• PSA: 0.00000
• LogP: 2.95440
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 227.99699
• Heavy Atom Count: 11
• Complexity: 117

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(CBr)C1=CC=CC=C1

Technology Process of Bromomethyl-dimethyl-phenylsilane

There total 6 articles about Bromomethyl-dimethyl-phenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

bromomethyldimethylsilyl chloride (16532-02-8) + phenylmagnesium bromide (100-58-3) → (bromomethyl)dimethylphenylsilane (22655-93-2)

Guidance literature:

In diethyl ether; for 16h; Heating;

DOI:10.1016/0022-328X(84)85094-9

Reference yield:

bromomethyldimethylsilyl chloride (16532-02-8) + bromobenzene (108-86-1,52753-63-6) → (bromomethyl)dimethylphenylsilane (22655-93-2)

Guidance literature:

With magnesium; Yield given. Multistep reaction; 1.) diethyl ether, 2.) diethyl ether, reflux 8 h;

Reference yield:

chloro-trimethyl-silane (75-77-4) + phenylmagnesium bromide → (bromomethyl)dimethylphenylsilane (22655-93-2)

Guidance literature:

With sulfuryl dichloride; 2,2'-azobis(isobutyronitrile); bromine; Yield given. Multistep reaction; 2.) Et₂O;

DOI:10.1039/c39890001256

upstream raw materials:

bromomethyldimethylsilyl chloride

chloromethyldimethylphenylsilane

bromobenzene

phenylmagnesium bromide

Downstream raw materials:

(dimethylphenylsilyl)acetic acid

trimethylphenylsilane

C₂₃H₃₂SSi₂

3-[(Dimethyl-phenyl-silanyl)-methoxy-methyl]-pentan-3-ol