Benzyl-methyl-phenylsulfanium;tetrafluoroborate

Base Information

• Chemical Name: Benzyl-methyl-phenylsulfanium;tetrafluoroborate
• CAS No.: 22900-27-2
• Molecular Formula: C14H15S.BF4
• Molecular Weight: 302.144
• Mol file: 22900-27-2.mol

Synonyms:SCHEMBL4854802

Chemical Property of Benzyl-methyl-phenylsulfanium;tetrafluoroborate

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 302.0923645
• Heavy Atom Count: 20
• Complexity: 185

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [B-](F)(F)(F)F.C[S+](CC1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Benzyl-methyl-phenylsulfanium;tetrafluoroborate

There total 3 articles about Benzyl-methyl-phenylsulfanium;tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

Benzyl phenyl sulfide (831-91-4) + trimethoxonium tetrafluoroborate (420-37-1) → benzylphenylmethyl sulfonium fluoroborate (22900-27-2)

Guidance literature:

DOI:10.1021/ja00380a020

Reference yield: 83.0%

methyl-phenyl-thioether (100-68-5) + benzyl bromide (100-39-0) → benzylphenylmethyl sulfonium fluoroborate (22900-27-2)

Guidance literature:

With silver tetrafluoroborate; In dichloromethane; for 48h; Ambient temperature;

DOI:10.1021/ja00327a010

Reference yield:

Benzyl phenyl sulfide (831-91-4) + methyl iodide (74-88-4) → benzylphenylmethyl sulfonium fluoroborate (22900-27-2)

Guidance literature:

With silver tetrafluoroborate;

DOI:10.1246/bcsj.42.312

upstream raw materials:

methyl-phenyl-thioether

benzyl bromide

Benzyl phenyl sulfide

methyl iodide

Downstream raw materials:

methyl-phenyl-thioether

O-benzyl-N-methyl benzohydroxamic acid

Refernces

• 1、 Saeva,Morgan. "MECHANISM OF ONE-ELECTRON ELECTROCHEMICAL REDUCTIVE CLEAVAGE REACTIONS OF SULFONIUM SALTS.". . p. 4121 - 4125. Retrieved 2007/10/02.