Sulfonium, chlorodimethyl-, chloride

Base Information

• Chemical Name: Sulfonium, chlorodimethyl-, chloride
• CAS No.: 23372-58-9
• Molecular Formula: C2H6ClS.Cl
• Molecular Weight: 133.042
• DSSTox Substance ID: DTXSID60472724
• Mol file: 23372-58-9.mol

Synonyms:Sulfonium, chlorodimethyl-, chloride;23372-58-9;SCHEMBL3126085;DTXSID60472724

Chemical Property of Sulfonium, chlorodimethyl-, chloride

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 131.9567268
• Heavy Atom Count: 5
• Complexity: 13.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[S+](C)Cl.[Cl-]

Technology Process of Sulfonium, chlorodimethyl-, chloride

There total 1 articles about Sulfonium, chlorodimethyl-, chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-dichloro-5-dichloromethylene-2-cyclopentene-1,4-dione (18964-31-3) + dimethyl sulfoxide (67-68-5,8070-53-9) → 2,5,5-trichloro-3-hydroxy-2-cyclopentene-1,4-dione (24963-41-5) + tetrachloro-cyclopent-4-ene-1,3-dione (15743-13-2) + chloro(dimethyl)sulfonium chloride (23372-58-9) + C5Cl2O2 + 2,3,5-trichloro-5-methylthio-2-cyclopentene-1,4-dione (86302-12-7) + 4,5-dichloro-4-cyclopentene-1,3-dione (3229-28-5)

Guidance literature:

Product distribution; Mechanism;

Reference yield: 97.0%

chloro(dimethyl)sulfonium chloride (23372-58-9) + (2R)-3-[(4-methoxybenzyl)oxy]-2-methylpropanol (136320-64-4) → C14H23ClO3S

Guidance literature:

With triethylamine; In dichloromethane; at -78 ℃;

DOI:10.1016/0040-4039(91)80594-V

Reference yield: 97.0%

chloro(dimethyl)sulfonium chloride (23372-58-9) + (2R,8S,9R)-9-Benzyloxy-7-hydroxy-1-(4-methoxy-benzyloxy)-2,4,4,8,10-pentamethyl-undecan-5-one (136320-69-9,136377-85-0) → C33H51ClO5S

Guidance literature:

With triethylamine; In dichloromethane; at -78 ℃;

DOI:10.1016/0040-4039(91)80594-V

upstream raw materials:

2,3-dichloro-5-dichloromethylene-2-cyclopentene-1,4-dione

dimethyl sulfoxide

Downstream raw materials:

chloro-methylsulfanyl-methane

4,4'-Diamino-3-methylthiomethyldiphenylmethane

4,4'-Diamino-3,3'-dimethylthiomethyl-diphenylmethane

4,4'-Diamino-3,3',5-trimethylthiomethyl-diphenylmethane

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