1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)-

Base Information

• Chemical Name: 1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)-
• CAS No.: 23956-51-6
• Molecular Formula: C11H16N2
• Molecular Weight: 176.261
• DSSTox Substance ID: DTXSID90463660
• Nikkaji Number: J1.842.506H
• Mol file: 23956-51-6.mol

Synonyms:23956-51-6;1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)-;SCHEMBL673967;SCHEMBL11558089;DTXSID90463660;UGRAWSWRHAFQSY-UHFFFAOYSA-N;N'-Benzylidene-N,N-dimethylethylenediamine

Chemical Property of 1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)-

Chemical Property:

• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 176.131348519
• Heavy Atom Count: 13
• Complexity: 146

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CN(C)CCN=CC1=CC=CC=C1

Technology Process of 1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)-

There total 4 articles about 1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

benzaldehyde (100-52-7) + N,N-dimethylethylenediamine (108-00-9) → N1-benzylidene-N2,N2-dimethylethane-1,2-diamine (23956-51-6)

Guidance literature:

DOI:10.1016/j.catcom.2011.07.019

Reference yield:

N'-(benzylideneamino)-N,N-diethylethan-1-amine (1749-16-2) → N1-benzylidene-N2,N2-dimethylethane-1,2-diamine (23956-51-6)

Guidance literature:

Multi-step reaction with 2 steps

1.1: tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; oxygen / acetone / 1 h / 20 °C / Glovebox

1.2: 1 h / 20 °C / Glovebox; Reflux

2.1: sodium sulfate / diethyl ether / 2 h / 20 °C / Reflux

With tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; oxygen; sodium sulfate; In diethyl ether; acetone;

DOI:10.1002/chem.201501003

Reference yield:

benzylidene phenylamine (538-51-2) + N,N-dimethylethylenediamine (108-00-9) → N1-benzylidene-N2,N2-dimethylethane-1,2-diamine (23956-51-6) + aniline (62-53-3)

Guidance literature:

In methanol; at 25 ℃; Rate constant;

DOI:10.1021/jo00384a063

upstream raw materials:

benzaldehyde

N,N-dimethylethylenediamine

benzylidene phenylamine

N'-(benzylideneamino)-N,N-diethylethan-1-amine

Downstream raw materials:

2-phenyl-3-[2-(N,N-dimethylamino)ethyl]-1,3-thiazolidin-4-one

N,N-dimethyl-N'-benzyl-1,2-ethanediamine

1-phenyl-2-aza-1,3-butadiene

1-phenyl-3-methoxy-2-aza-1-butene