Phosphonic acid, [1-(benzoyloxy)ethenyl]-, dimethyl ester

Base Information

Chemical Name:Phosphonic acid, [1-(benzoyloxy)ethenyl]-, dimethyl ester
CAS No.:241496-28-6
Molecular Formula:C11H13O5P
Molecular Weight:256.195
Hs Code.:
DSSTox Substance ID:DTXSID70451383
Nikkaji Number:J1.590.738J
Mol file:241496-28-6.mol

Synonyms:241496-28-6;Phosphonic acid, [1-(benzoyloxy)ethenyl]-, dimethyl ester;DTXSID70451383;dimethyl 1-benzoyloxy-ethenephosphonate;1-(Benzoyloxy)vinylphosphonic acid dimethyl ester

Suppliers and Price of Phosphonic acid, [1-(benzoyloxy)ethenyl]-, dimethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Phosphonic acid, [1-(benzoyloxy)ethenyl]-, dimethyl ester

Chemical Property:

XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:6
Exact Mass:256.05006051
Heavy Atom Count:17
Complexity:325

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COP(=O)(C(=C)OC(=O)C1=CC=CC=C1)OC

Technology Process of Phosphonic acid, [1-(benzoyloxy)ethenyl]-, dimethyl ester

There total 1 articles about Phosphonic acid, [1-(benzoyloxy)ethenyl]-, dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 93-97-0
benzoic acid anhydride

: 17674-28-1
dimethyl acetylphosphonate

: 241496-28-6
1-(dimethoxyphosphoryl)vinylbenzoate

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 0 - 25 ℃; for 0.25h;
DOI:10.1021/ol9906099

Reference yield: 100.0%

: 241496-28-6
1-(dimethoxyphosphoryl)vinylbenzoate

: 1333-74-0
hydrogen

: (R)-(+)-1-benzoyloxy-1-dimethylphosphonylethane

Guidance literature:: With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; C₃₈H₂₇F₁₂NP₂; In dichloromethane; at 20 ℃; for 24.25h; under 7600.51 Torr; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/adsc.200800418

Reference yield: 100.0%

: 241496-28-6
1-(dimethoxyphosphoryl)vinylbenzoate

: 1333-74-0
hydrogen

: (S)-(-)-1-benzoyloxy-1-dimethylphosphonylethane

Guidance literature:: With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (S)-HH-Phos; In dichloromethane; at 20 ℃; for 24.25h; under 7600.51 Torr; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/adsc.200800418