(But-3-en-2-yl)(triphenyl)stannane

Base Information

Chemical Name:(But-3-en-2-yl)(triphenyl)stannane
CAS No.:2591-51-7
Molecular Formula:C₂₂H₂₂Sn
Molecular Weight:405.127
Hs Code.:
DSSTox Substance ID:DTXSID80566018
Mol file:2591-51-7.mol

Synonyms:(But-3-en-2-yl)(triphenyl)stannane;2591-51-7;DTXSID80566018

Suppliers and Price of (But-3-en-2-yl)(triphenyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (But-3-en-2-yl)(triphenyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:5
Exact Mass:406.074353
Heavy Atom Count:23
Complexity:311

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C=C)[Sn](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of (But-3-en-2-yl)(triphenyl)stannane

There total 10 articles about (But-3-en-2-yl)(triphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 4784-77-4,29576-14-5,39616-19-8
(E/Z)-crotyl bromide

: 894-09-7
iodotriphenylstannane

: 2591-43-7,2591-51-7
(1-methyl-2-propenyl)triphenylstannane

Guidance literature:: With ammonium chloride; zinc; In tetrahydrofuran; water; Ph3SnI is added to THF/H2O (NH4Cl saturated) mixt. with excess of zinc powder, crotyl bromide (mixt. of trans, cis and α 76:9:15) is added dropwise under stirring within 5 min, filtn. after 1 h of mixing, THF is removed; residue is treated with chlorroform, extn. (chloroform), drying (Na2SO4), solvent is evapd., treated with petroleum ether or n-hexane, solvent is evapd., crystd. (ethanol), isomeric mixt. of α, trans and cis with α as major component;
DOI:10.1021/om00015a025

Reference yield: 80.0%

: 639-58-7
triphenyltin chloride

: 6088-87-5,53247-17-9
2-butenylmagnesium bromide

: 2591-43-7,2591-51-7
(E/Z)-triphenyl crotylstannane

Guidance literature:: In diethyl ether;

Reference yield: 70.0%

: 4784-77-4,29576-14-5,39616-19-8
(E/Z)-crotyl bromide

: 76-87-9
triphenyltin(IV) hydroxide

: 2591-43-7,2591-51-7
(1-methyl-2-propenyl)triphenylstannane

Guidance literature:: With ammonium chloride; zinc; In tetrahydrofuran; water; byproducts: Ph3SnSnPh3; Ph3SnOH is added to THF/H2O (NH4Cl saturated) mixt. with excess of zinc powder, crotyl bromide (mixt. of trans, cis and α 76:9:15) is added dropwise under stirring within 5 min, filtn. after 1 h of mixing, THF is removed; residue is treated with chlorroform, extn. (chloroform), drying (Na2SO4), solvent is evapd., treated with petroleum ether or n-hexane, solvent is evapd., crystd. (ethanol), isomeric mixt. of α, trans and cis with α as major component;
DOI:10.1021/om00015a025