Triphenylstannanylium;iodide

Base Information

• Chemical Name: Triphenylstannanylium;iodide
• CAS No.: 894-09-7
• Molecular Formula: C18H15 I Sn
• Molecular Weight: 476.932
• Hs Code.: 2931900090
• Mol file: 894-09-7.mol

Synonyms:SCHEMBL1030209

Chemical Property of Triphenylstannanylium;iodide

Chemical Property:

• Vapor Pressure: 2.02E-07mmHg at 25°C
• Melting Point: 117-121°C
• Boiling Point: 436.7°C at 760 mmHg
• Flash Point: 217.9°C
• PSA: 0.00000
• LogP: 3.08850
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 477.92405
• Heavy Atom Count: 20
• Complexity: 202

Purity/Quality:

98%min ^*data from raw suppliers

IODOTRIPHENYLTIN Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s): A poison. TWA 0.1 mg(Sn)/m³; STEL 0.2 mg(Sn)/m³ (skin).
• Hazard Codes: A poison. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
• Statements: 20/21/22
• Safety Statements: 22-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn+](C2=CC=CC=C2)C3=CC=CC=C3.[I-]

Technology Process of Triphenylstannanylium;iodide

There total 50 articles about Triphenylstannanylium;iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

[1]naphthyl-triphenyl stannane (81134-67-0) + iodine (7553-56-2,12190-71-5,8031-47-8) → iodotriphenylstannane (894-09-7)

Guidance literature:

In tetrachloromethane; byproducts: naphthyl iodide; react. of I2 with tin compd. soln. (molar ratio 1:1), 25°C, 1h;

Reference yield: 79.9%

cyclopenta-2,4-dienyl-triphenyl stannane (1238-38-6) → iodotriphenylstannane (894-09-7)

Guidance literature:

With I₂; In tetrachloromethane; under N2, dropwise addn. of I2 in CCl4 to a soln. of the Sn compound inCCl4 at 60°C, disappearance of violet colour; concg. the soln. after complete addn., pptn. recrystn. (petroleum ether(40 - 60°));

Reference yield: 72.6%

bis(triphenyltin) sulfide (77-80-5) + tetramethylstannane (594-27-4) → iodotriphenylstannane (894-09-7) + sulfur (7704-34-9)

Guidance literature:

With iodine; In chloroform; hexaphenyldistannathiane and tetramethylstannane are treated with iodine in chloroform, stirred at 25°C for 13 h in the dark; evapn., extn. (acetonitrile), concn. of soluble fraction yields Sn compd., insol. fraction is indentified as sulfur;

DOI:10.1021/om00093a026

upstream raw materials:

triphenyltin chloride

iodomethylbenzene

triphenylstannane

methyl iodide

Downstream raw materials:

triphenylstannane

triphenyltin chloride

diphenyl isopropyl tin iodide

heptyltriphenylstannane

Refernces

• 1、 Ng, S. -W.,Zuckerman, J. J.. "SYNTHESIS OF TRIPHENYLPHOSPHONOPROPIONBETAINETRIORGANOTIN(IV) SALTS +X-, BY NUCLEOPHILIC DISPLACEMENT OF ANIONS FROM TRIORGANOTINS". . p. 257 - 276. Retrieved 1982.
• 2、 Aitken, Clare T.,Onyszchuk, Mario. "PREPARATION AND SPECTROSCOPIC STUDIES OF SOME CYCLIC UREA ADDUCTS OF TRIPHENYL-THIN AND -LEAD HALIDES". . p. 149 - 158. Retrieved 1985.
• 3、 Rybakova,Syutkina,Petrov. "Reactions of organolanthanide compounds RLnI (Ln = Yb, Eu, Sm) with organic derivatives of silicon, tin, lead, and antimony". . p. 244 - 246. Retrieved 2007/10/03.
• 4、 Syutkina,Rybakova,Novgorodova,Petrov. "Cleavage of Sn-Sn Bonds in Hexaalkyl(aryl)stannanes under the Action of Yb(II) Derivatives". . p. 76 - 78. Retrieved 2007/10/03.