4,6-Dimethyl-1,3-dioxane

Base Information

• Chemical Name: 4,6-Dimethyl-1,3-dioxane
• CAS No.: 26864-43-7
• Molecular Formula: C6H12O2
• Molecular Weight: 116.15800
• Mol file: 26864-43-7.mol

Synonyms:4,6-dimethyl-[1,3]dioxane;4,6-Dimethyl-1,3-dioxan;

Chemical Property of 4,6-Dimethyl-1,3-dioxane

Chemical Property:

• Boiling Point: 125.8±8.0 °C(Predicted)
• PSA: 18.46000
• Density: 0.903±0.06 g/cm3(Predicted)
• LogP: 1.15780

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4,6-Dimethyl-1,3-dioxane

There total 4 articles about 4,6-Dimethyl-1,3-dioxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

→ 4,6-dimethyl-1,3-dioxane (26864-43-7)

Guidance literature:

With bismuth(lll) trifluoromethanesulfonate; In 1,4-dioxane; at 40 ℃; for 0.5h; Sealed tube; Sonication;

Reference yield:

pentane-1,3-diol (1825-14-5,3950-21-8,36402-52-5,42075-32-1,72345-23-4,625-69-4) → 4,6-dimethyl-1,3-dioxane (26864-43-7)

Guidance literature:

With bismuth(lll) trifluoromethanesulfonate; In 1,4-dioxane; at 100 ℃; for 3h; Sealed tube;

DOI:10.1002/cssc.201902880

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + pentane-1,3-diol (1825-14-5,3950-21-8,36402-52-5,42075-32-1,72345-23-4,625-69-4) → 4,6-dimethyl-1,3-dioxane (26864-43-7)

Guidance literature:

With aluminium(III) triflate; [Ru(1,1,1-tris(diphenylphosphinomethyl)ethane)(trimethylenemethane)]; hydrogen; In 1,4-dioxane; at 80 ℃; for 18h; under 60006 Torr; Catalytic behavior; Autoclave; Schlenk technique;

DOI:10.1002/chem.201901660

upstream raw materials:

carbon dioxide

pentane-1,3-diol

Refernces

• 1、 Beydoun, Kassem,Klankermayer, Jürgen. "Efficient Plastic Waste Recycling to Value-Added Products by Integrated Biomass Processing". . p. 488 - 492. Retrieved 2020/01/24.