Benzene, 1,1'-(1-methoxy-1,2-ethanediyl)bis-

Base Information

• Chemical Name: Benzene, 1,1'-(1-methoxy-1,2-ethanediyl)bis-
• CAS No.: 27820-29-7
• Molecular Formula: C15H16O
• Molecular Weight: 212.291
• DSSTox Substance ID: DTXSID70454677
• Nikkaji Number: J807.933A
• Mol file: 27820-29-7.mol

Synonyms:Benzene, 1,1'-(1-methoxy-1,2-ethanediyl)bis-;27820-29-7;1,2-Diphenyl-1-methoxyethane;SCHEMBL4056401;DTXSID70454677

Chemical Property of Benzene, 1,1'-(1-methoxy-1,2-ethanediyl)bis-

Chemical Property:

• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 212.120115130
• Heavy Atom Count: 16
• Complexity: 178

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(CC1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Benzene, 1,1'-(1-methoxy-1,2-ethanediyl)bis-

There total 21 articles about Benzene, 1,1'-(1-methoxy-1,2-ethanediyl)bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

benzyl chloride (100-44-7) + (Methoxy-methylselanyl-methyl)-benzene (153992-06-4) → (1-methoxyethane-1,2-diyl)dibenzene (27820-29-7)

Guidance literature:

With tert.-butyl lithium; In tetrahydrofuran; at -78 - 25 ℃;

DOI:10.1016/S0040-4039(97)01410-X

Reference yield: 71.0%

Thiocarbonic acid O-(2-methoxy-1,2-diphenyl-ethyl) ester O-phenyl ester → (1-methoxyethane-1,2-diyl)dibenzene (27820-29-7)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); TMSO-(SiHMeO)n-TMS; bis(tri-n-butyltin)oxide; butan-1-ol; In toluene; at 80 ℃; for 24h;

DOI:10.1021/ja971400y

Reference yield: 71.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + methanol (67-56-1) + trimethylphenylsilane (768-32-1) → (1-methoxyethane-1,2-diyl)dibenzene (27820-29-7)

Guidance literature:

With 1-hydroxy-1,2-benzodioxol-3-(1H)-one; (triphenylphosphine)gold(I) chloride; toluene-4-sulfonic acid; In α,α,α-trifluorotoluene; at 70 ℃; for 2h;

DOI:10.1002/chem.201103061

upstream raw materials:

1,2-Diphenylethanol

methyl iodide

methanol

(E)-1,2-diphenyl-ethene

Downstream raw materials:

stilbene

4,5-diphenyl-pent-1-ene