Peroxide, 1,1-dimethylethyl 1-phenylethyl

Base Information

• Chemical Name: Peroxide, 1,1-dimethylethyl 1-phenylethyl
• CAS No.: 28047-94-1
• Molecular Formula: C12H18O2
• Molecular Weight: 194.274
• Mol file: 28047-94-1.mol

Synonyms:

Chemical Property of Peroxide, 1,1-dimethylethyl 1-phenylethyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Peroxide, 1,1-dimethylethyl 1-phenylethyl

There total 16 articles about Peroxide, 1,1-dimethylethyl 1-phenylethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

tert.-butylhydroperoxide (75-91-2) + ethylbenzene (100-41-4,27536-89-6) → 1-Phenylethanol (98-85-1,13323-81-4) + 1,1-dimethylethyl-1-phenylethyl peroxide (28047-94-1) + acetophenone (98-86-2)

Guidance literature:

With copper(II) choride dihydrate; tetrabutyl-ammonium chloride; sodium carbonate; 2,2′‐biquinoline‐4,4′‐dicarboxylic acid dipotassium salt; In water; at 20 ℃; for 17h; Green chemistry;

DOI:10.1515/chem-2020-0018

Reference yield: 79.0%

→ 1,1-dimethylethyl-1-phenylethyl peroxide (28047-94-1)

Guidance literature:

With sodium hydroxide; (C₄H₉)NBr; tetrabutylammonium borohydride; In dichloromethane; at 0 ℃; for 0.166667h;

Reference yield: 62.0%

tert.-butylhydroperoxide (75-91-2) + ethylbenzene (100-41-4,27536-89-6) → 1,1-dimethylethyl-1-phenylethyl peroxide (28047-94-1)

Guidance literature:

With acetic acid; ferric nitrate; In pyridine; at 60 ℃; for 18h;

DOI:10.1039/c39940001823

upstream raw materials:

styrene

tert.-butylhydroperoxide

ethylbenzene

1-Phenylethanol

Downstream raw materials:

(S)-1-phenylethanol

acetophenone

diphenyldisulfane

tert-butyl alcohol

Refernces

• 1、 Bloodworth,A.J.,Bylina,G.S.. "-". . p. 2433 - 2438. Retrieved 1972.
• 2、 Li, Peihe,Wang, Yingying,Wang, Xia,Wang, Yin,Liu, Ying,Huang, Keke,Hu, Jing,Duan, Limei,Hu, Changwen,Liu, Jinghai. "Selective Oxidation of Benzylic C-H Bonds Catalyzed by Cu(II)/{PMo12}". . p. 3101 - 3109. Retrieved 2020/03/23.
• 3、 Huang, Runkun,Cao, Changyan,Liu, Jian,Sun, Dongping,Song, Weiguo. "N-Doped carbon nanofibers derived from bacterial cellulose as an excellent metal-free catalyst for selective oxidation of arylalkanes". supporting information. p. 1935 - 1938. Retrieved 2019/05/02.