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Naphthalinsulfonsaeure-trimethylsilylester
sodium 1-naphthalenesulfonate
Conditions | Yield |
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With sodium hydrogencarbonate In tetrachloromethane for 0.333333h; Yield given; |
Conditions | Yield |
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With trichlorophosphate In sulfolane; acetonitrile at 68 - 72℃; for 0.666667h; | 94% |
With phosphorus pentachloride | |
With phosphorus pentachloride at 125℃; aus bei 180grad getrocknetem Edukt1 und Behandeln nach dem Abkuehlen mit Eis und mit Wasser; | |
With chlorine-triphenylphosphine In acetonitrile for 15h; Ambient temperature; |
Conditions | Yield |
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Stage #1: (1R,2R,4S)-2-(3-chlorophenyl)-1-(4-chlorophenyl)-4-((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)-4-methylhept-6-en-1-ol; toluene; Methanesulfonic anhydride With 2,6-dimethylpyridine at 75℃; for 12h; Stage #2: With sulfuric acid In dichloromethane; water at 20℃; for 0.5h; Stage #3: sodium 1-naphthalenesulfonate In dichloromethane; water | A n/a B n/a C 90% |
Conditions | Yield |
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In ethanol; water High Pressure; mixt. sodium 1-naphthalenesulfonate and AgNO3 in water was stirred for 5min and filtered, pyrazine in EtOH was added, transferred to Teflon-lin ed stainless steel autoclave and heated at 140°C for 1 day; cooling to room temp. at 10°C/h; elem. anal.; | 85% |
Conditions | Yield |
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With dipotassium peroxodisulfate In water at 70℃; for 24h; Green chemistry; | 85% |
sodium 1-naphthalenesulfonate
4-methoxyphenyl magnesium bromide
1-(4-methoxyphenyl)naphthalene
Conditions | Yield |
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With bis(tricyclohexylphosphine)nickel(II) dichloride In tetrahydrofuran at 20℃; for 20h; Sealed tube; Inert atmosphere; | 83% |
Conditions | Yield |
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With triphenylphosphine; 18-crown-6 ether; iodine In benzene for 35h; Heating; | 70% |
With 18-crown-6 ether; iodine; triphenylphosphine In benzene for 35h; Heating; | 70 % Chromat. |
Multi-step reaction with 2 steps 1: PCl5 / 125 °C / aus bei 180grad getrocknetem Edukt1 und Behandeln nach dem Abkuehlen mit Eis und mit Wasser 2: zinc dust; water / 60 °C / dann bei 70grad, anschliessend Behandeln mit verd. Salzsaeure und Zinkstaub View Scheme |
Conditions | Yield |
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In water High Pressure; mixt. sodium 1-naphthalenesulfonate and AgNO3 in water was stirred for 5min and filtered, picoline was added, react. mixt. was transferred to T eflon-lined stainless steel autoclave and heated at 140°C for 1 day; cooling to room temp. at 10°C/h; elem. anal.; | 70% |
Conditions | Yield |
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With NH4OH In water; acetonitrile aq. soln. hexamethylenetetramine was added dropwise to soln. AgNO3 and sodium 1-naphthalenesulfonate in aq. MeCN (1:1) for 10 min; aq. soln. NH3 was added and kept in the dark for several days; elem. anal.; | 70% |
sodium 1-naphthalenesulfonate
triphenylphosphine
tris(triphenylphosphine)(1-naphthalenesulfonato)silver(I)
Conditions | Yield |
---|---|
In methanol; water mixt. of Na salt of ligand and AgNO3 in H2O stirred for 5 min; filtered;PPh3 in MeOH added to filtrate; ppt. dissolved in min. MeCN; crystd. by slow evapn. in the dark for several d; elem. anal.; | 67% |
The Sodium 1-naphthalenesulfonate, with the CAS registry number 130-14-3 and EINECS registry number 204-976-0, has the systematic name of sodium naphthalene-1-sulfonate. It belongs to the product category of Intermediates of Dyes and Pigments. And the molecular formula of the chemical is C10H7NaO3S.
The characteristics of this chemical are as followings: (1)H-Bond Donor 0; (2)H-Bond Acceptor 3; (3)Rotatable Bond Count 1; (4)Exact Mass 230.001359; (5)MonoIsotopic Mass 230.001359; (6)Topological Polar Surface Area 65.6; (7)Heavy Atom Count 15; (8)Formal Charge 0; (9)Complexity 296; (10)Isotope Atom Count 0; (11)Defined Atom StereoCenter Count 0; (12)Undefined Atom StereoCenter Count 0; (13)Defined Bond StereoCenter Count 0; (14)Undefined Bond StereoCenter Count 0; (15)Covalently-Bonded Unit Count 2.
Uses of Sodium 1-naphthalenesulfonate: It can be used to produce naphthalene-1-sulfonyl chloride. This reaction will need reagent POCl3, menstruum acetonitrile and tetrahydrothiophene 1,1-dioxide. The reaction time is 40 minutes with temperature of 68-72°C, and the yield is about 94%.
You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective clothing, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.
Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: [Na+].[O-]S(=O)(=O)c2cccc1ccccc12
(2)InChI: InChI=1/C10H8O3S.Na/c11-14(12,13)10-7-3-5-8-4-1-2-6-9(8)10;/h1-7H,(H,11,12,13);/q;+1/p-1
(3)InChIKey: HIEHAIZHJZLEPQ-REWHXWOFAJ