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Succinoyl Peroxide

  • Name Succinoyl Peroxide
  • EINECS204-611-5
  • CAS No. 123-23-9
  • Density1.493 g/cm3
  • PSA127.20000
  • LogP-0.28260
  • Solubilityvery soluble in water
  • Melting Point133°C (rough estimate)
  • FormulaC8H10 O8
  • Boiling Point453.3 °C at 760 mmHg
  • Molecular Weight234.163
  • Flash Point183.3 °C
  • Transport InformationUN 2135
  • AppearanceFine white odorless powder.
  • SafetyAn irritant. Explodes on contact with flame. When heated to decomposition it emits acrid smoke and irritating fumes. See also PEROXIDES, ORGANIC.
  • Risk CodesN/A
  • Molecular Structure
    Molecular Structure of 123-23-9 (SUCCINIC ACID PEROXIDE)
  • Hazard SymbolsFire risk in contact with combustible materials, oxidizing agent. Toxic by ingestion and inhalation, irritant to skin.
  • SynonymsFire risk in contact with combustible materials, oxidizing agent. Toxic by ingestion and inhalation, irritant to skin.
  • Article Data10

Succinoyl Peroxide Synthetic route

108-30-5

succinic acid anhydride

123-23-9

peroxydicuccinic acid

Conditions
ConditionsYield
With dihydrogen peroxide
With dihydrogen peroxide
With dihydrogen peroxide
123-23-9

peroxydicuccinic acid

81-64-1

1,4-dihydroxy-9,10-anthracenedione

2-(2-carboxyethyl)-1,4-dihydroxy-9,10-anthraquinone

Conditions
ConditionsYield
With boric acid; acetic anhydride at 95 - 98℃; for 5h;79%
123-23-9

peroxydicuccinic acid

158526-26-2

2,5,8-trihydroxy-6,7-dichloro-1,4-naphthoquinone

187149-28-6

3-(6,7-dichloro-3,5,8-trihydroxy-1,4-dioxo-1,4-dihydro-naphthalen-2-yl)-propionic acid

Conditions
ConditionsYield
In tert-butyl alcohol Heating;38%
123-23-9

peroxydicuccinic acid

129-43-1

1-hydroxyanthraquinone

2-(2-carboxyethyl)-1-hydroxy-9,10-anthraquinone

Conditions
ConditionsYield
With boric acid; acetic anhydride at 80℃; for 10h;33%
605-94-7

2,3-Dimethoxy-5-methyl-1,4-benzoquinone

123-23-9

peroxydicuccinic acid

58186-10-0

3-(2,3-Dimethoxy-5-methyl-1,4-benzoquinon-6-yl)propionic acid

Conditions
ConditionsYield
In acetic acid at 90℃; for 4h;32%
56-23-5

tetrachloromethane

123-23-9

peroxydicuccinic acid

A

108-30-5

succinic acid anhydride

B

124-04-9

Adipic acid

83-72-7

2-Hydroxy-1,4-naphthoquinone

123-23-9

peroxydicuccinic acid

3,4-dihydro-benzo[g]chromene-2,5,10-trione

Conditions
ConditionsYield
With methanol; acetic acid
123-23-9

peroxydicuccinic acid

58-27-5

menadione

84978-48-3

3-(3-methyl-1,4-naphthoquinon-2-yl)-propionic acid

Conditions
ConditionsYield
With acetic acid
123-23-9

peroxydicuccinic acid

A

124-04-9

Adipic acid

B

15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

Conditions
ConditionsYield
at 280℃;
123-23-9

peroxydicuccinic acid

54305-79-2

Peroxydisuccinyldichlorid

Conditions
ConditionsYield
With thionyl chloride

Succinoyl Peroxide Consensus Reports

Reported in EPA TSCA Inventory.

Succinoyl Peroxide Specification

Succinoyl Peroxide is also a chemical of molecular forumula C8-H10-O8. Its CAS Registry number is 123-23-9 and it is also called 4,4'-Dioxybis(4-oxobutanoic acid); Alfozono; Alphozone; Bis(3-carboxypropionyl) peroxide; Butanoic acid, 4,4'-dioxybis(4-oxo-; Disuccinic acid peroxide; Disuccinoyl peroxide; Peroxide, bis(3-carboxypropionyl); Peroxydisuccinic acid; Peroyl SA; Succinic acid peroxide; Succinic monoperoxyanhydride; Succinic peroxide. Succinoyl Peroxide is white odorless solid, used as polymerization catalyst, antiseptic, and disinfectant.

Physical properties about Succinoyl Peroxide are: (1)ACD/LogP: -1.001; (2)ACD/LogD (pH 5.5): -3.96; (3)ACD/LogD (pH 7.4): -5.74; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 1.00; (7)ACD/KOC (pH 7.4): 1.00; (8)#H bond acceptors: 8 ; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 9; (11)Index of Refraction: 1.496; (12)Molar Refractivity: 45.791 cm3; (13)Molar Volume: 156.805 cm3; (14)Polarizability: 18.153 10-24cm3; (15)Surface Tension: 63.984001159668 dyne/cm; (16)Density: 1.493 g/cm3; (17)Flash Point: 183.27 °C; (18)Enthalpy of Vaporization: 78.109 kJ/mol; (19)Boiling Point: 453.287 °C at 760 mmHg

You can still convert the following datas into molecular structure:
(1)InChI=1S/C8H10O8/c9-5(10)1-3-7(13)15-16-8(14)4-2-6(11)12/h1-4H2,(H,9,10)(H,11,12);
(2)InChIKey=MKTOIPPVFPJEQO-UHFFFAOYSA-N;
(3)SmilesC(OOC(CCC(O)=O)=O)(CCC(O)=O)=O;

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD intraperitoneal > 15600ug/kg (15.6mg/kg)   "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 2, Pg. 302, 1950.

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