- Tetrahydrofurfuryl acetate
- Tetrahydrofurfuryl acrylate
- Tetrahydrofurfuryl alcohol
- Tetrahydrofurfuryl benzoate
- Tetrahydrofurfuryl bromide
- Tetrahydrofurfuryl butyrate
- Tetrahydrofurfuryl chloride
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Cas Database |
| Name |
Tetrahydrofurfuryl methacrylate |
EINECS | 219-529-5 |
| CAS No. | 2455-24-5 | Density | 1.044 |
| PSA | 35.53000 | LogP | 1.28470 |
| Solubility | 18.99g/L at 20℃ | Melting Point |
N/A |
| Formula | C9H14 O3 | Boiling Point | 52 °C0.4 mm Hg(lit.) |
| Molecular Weight | 170.208 | Flash Point | 91 ºC |
| Transport Information | 3272 | Appearance | N/A |
| Safety | 36 | Risk Codes | 10-36/37/38 |
| Molecular Structure |
|
Hazard Symbols | R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.; |
| Synonyms |
Methacrylicacid, tetrahydrofurfuryl ester (7CI,8CI); Furfuryl alcohol, tetrahydro-,methacrylate (8CI); Acryester THF; NSC 32634; SR 203; Sartomer SR 203;Tetrahydrofurfuryl methacrylate |
Article Data | 7 |
Tetrahydrofurfuryl methacrylate Synthetic route
- 97-99-4
Tetrahydrofurfuryl alcohol
- 80-62-6
methacrylic acid methyl ester
- 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
| Conditions | Yield |
|---|---|
| With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; di(n-butyl)tin oxide In 2-Methylpentane; cyclohexane at 85 - 100℃; for 12h; Temperature; | 95% |
| 2-methyl-propan-2-ol; lanthanum tri-tert-butylate at 25℃; for 2h; | 32 %Chromat. |
| sodium ethanolate | 15 %Chromat. |
| With sulfuric acid; benzene |
- 97-99-4
Tetrahydrofurfuryl alcohol
- 97-63-2
methyl methacrylate
- 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
| Conditions | Yield |
|---|---|
| With sulfuric acid |
- 97-99-4
Tetrahydrofurfuryl alcohol
- 79-41-4
poly(methacrylic acid)
- 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
| Conditions | Yield |
|---|---|
| With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; |
| Conditions | Yield |
|---|---|
| In 2-methyltetrahydrofuran at 90℃; for 4h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction; | 79% |
- 75-91-2
tert.-butylhydroperoxide
- 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
- 66-99-9
β-naphthaldehyde
| Conditions | Yield |
|---|---|
| With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 75% |
- 75-91-2
tert.-butylhydroperoxide
- 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
- 123-11-5
4-methoxy-benzaldehyde
| Conditions | Yield |
|---|---|
| With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 74% |
- 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
- 34535-98-3
D,L-cis-phenylcyclopropylamine
| Conditions | Yield |
|---|---|
| With C60H100N4O12Rh2 In hexane at 20℃; for 18h; Schlenk technique; Inert atmosphere; | A 11% B 74% |
- 75-91-2
tert.-butylhydroperoxide
- 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
- 591-31-1
3-methoxy-benzaldehyde
| Conditions | Yield |
|---|---|
| With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 73% |
- 75-91-2
tert.-butylhydroperoxide
- 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
- 100-52-7
benzaldehyde
- 1415690-09-3
(tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-oxo-4-phenylbutanoate
| Conditions | Yield |
|---|---|
| With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 70% |
| With iron(II) chloride In decane; acetonitrile at 85℃; for 1h; Inert atmosphere; | 61% |
- 75-91-2
tert.-butylhydroperoxide
- 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate
- 459-57-4
4-fluorobenzaldehyde
| Conditions | Yield |
|---|---|
| With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere; | 67% |
Tetrahydrofurfuryl methacrylate Chemical Properties
Molecular Structure of Tetrahydrofurfuryl methacrylate (CAS No.2455-24-5):
Molecular Formula: C9H14O3
Molecular Weight:
CAS No: 2455-24-5
H bond acceptors: 3
H bond donors: 0
Freely Rotating Bonds: 4
Polar Surface Area: 35.53 Å2
Index of Refraction: 1.452
Molar Refractivity: 44.62 cm3
Molar Volume: 165.2 cm3
Surface Tension: 33.7 dyne/cm
Density: 1.03 g/cm3
Flash Point: 105.6 °C
Enthalpy of Vaporization: 50.29 kJ/mol
Boiling Point: 265 °C at 760 mmHg
Vapour Pressure: 0.0094 mmHg at 25°C
IUPAC Name: Oxolan-2-ylmethyl 2-methylprop-2-enoate
InChI: InChI=1/C9H14O3/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
InChIKey: LCXXNKZQVOXMEH-UHFFFAOYAZ
Std. InChI: InChI=1S/C9H14O3/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
Std. InChIKey: LCXXNKZQVOXMEH-UHFFFAOYSA-N
Product Categories: FuransMonomers;Acrylic Monomers;Building Blocks;Heterocyclic Building Blocks;Methacrylate
Tetrahydrofurfuryl methacrylate Safety Profile
Risk Statements: 10-36/37/38
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 36
S36:Wear suitable protective clothing.
RIDADR: 3272
WGK Germany: 1
HazardClass: 3
PackingGroup: III
Hazardous Substances Data: 2455-24-5
Tetrahydrofurfuryl methacrylate Specification
Tetrahydrofurfuryl methacrylate (CAS No.2455-24-5), its synonyms are 2-Propenoic acid, 2-methyl-, (tetrahydro-2-furanyl)methyl ester ; Methacrylic acid, tetrahydrofurfuryl ester (8CI) ; Tetrahydro-2-furanylmethyl methacrylate ; Tetrahydrofuran-2-ylmethyl 2-methylprop-2-enoate ; Tetrahydrofuran-2-ylmethyl methacrylate ; 2-Methyl-acrylic acid tetrahydro-furan-2-ylmethyl ester .
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