Aromatic ketimines often contain conjugated π-systems, and these can engage in π-π interactions with the chiral ligands or catalysts. These interactions can affect the orientation of the substrate during the reduction process, leading to enantioselectivity.
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(E)-2-methoxy-N-(1-phenylethylidene)aniline
1,3-diphenyl-6-(tert-butyl) fulvene
4-(3-fluorophenylazo)-3-fluoro phenol
