Some chiral catalysts or ligands can form specific chiral pockets that can accommodate one enantiomer of the substrate more favorably than the other. This results in preferential reduction of one enantiomer, leading to high enantioselectivity.
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(E)-2-methoxy-N-(1-phenylethylidene)aniline
(S)-N-(1-benzyl-2-hydroxy-ethyl)-2-(diphenylphosphino)benzamide
